IP Library Granted Patent US 10,093,869
Granted Patent B2
US 10,093,869 · App. 14/859,480 · Granted Oct 9, 2018

Decontamination of sulfur contaminants from hydrocarbons

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Quick Facts
Patent No.
US 10,093,869
App. No.
14/859,480
Granted
Oct 9, 2018
Kind
B2
Abstract

A method for removing hydrogen sulfide from a hydrocarbon. The method comprises introducing methylmorpholine-N-oxide to a vessel, wherein the vessel comprises the hydrocarbon, and wherein the hydrocarbon comprises hydrogen sulfide; and treating the hydrocarbon by allowing the methylmorpholine-N-oxide to react with the hydrogen sulfide.

Claims (11)

1. A method for removing hydrogen sulfide from a hydrocarbon, comprising:

(A) introducing methylmorpholine-N-oxide to a vessel, wherein the vessel comprises the hydrocarbon, and wherein the hydrocarbon comprises hydrogen sulfide, wherein the hydrogen sulfide is present in an amount of at least about 1,000 ppm; and

(B) treating the hydrocarbon by allowing the methylmorpholine-N-oxide to react with the hydrogen sulfide, wherein treating the hydrocarbon comprises converting the hydrogen sulfide to elemental sulfur, wherein the elemental sulfur is removed from the vessel by way of a centrifuge;

(C) recirculating between about one volume of the centrifuged hydrocarbon comprising the methylmorpholine-N-oxide in the vessel to about ten volumes of the centrifuged hydrocarbon comprising the methylmorpholine-N-oxide in the vessel, wherein the recirculating further comprises heating the hydrocarbon.

2. The method of claim 1 , wherein the hydrocarbon comprises a hydrocarbon fluid.

3. The method of claim 1 , wherein the hydrocarbon comprises a hydrocarbon gas.

4. The method of claim 1 , wherein the concentration of the methylmorpholine-N-oxide in the hydrocarbon is between about 0.01 weight volume % and about 60 weight volume % of the hydrocarbon.

5. The method of claim 1 , wherein the methylmorpholine-N-oxide solution is introduced to the hydrocarbon in an amount to provide a mole ratio of methylmorpholine-N-oxide to hydrogen sulfide in the vessel from about 1.0 mole methylmorpholine-N-oxide: 1.0 mole hydrogen sulfide to about about 3.0 moles methylmorpholine-N-oxide: 1.0 mole hydrogen sulfide.

6. The method of claim 1 , further comprising introducing steam to the vessel.

7. The method of claim 6 , wherein the steam comprises 150 psig steam or less.

8. The method of claim 7 , further comprising introducing the steam to the vessel to increase the temperature of the hydrocarbon to a temperature of from about 70° F. to about 150° F.

Assignments (5)
MERGER Recorded Mar 15, 2025
From: CR3 ZYMEFLOW, INC.
To: ZYMEFLOW, INC.
Reel/Frame 070523/0169 →
MERGER Recorded Mar 13, 2025
From: TRISTAR GLOBAL ENERGY SOLUTIONS, INC.
To: CR3 ZYMEFLOW, INC.
Reel/Frame 070508/0396 →
MERGER Recorded Mar 12, 2025
From: UNITED LABORATORIES INTERNATIONAL, LLC
To: TRISTAR GLOBAL ENERGY SOLUTIONS, INC.
Reel/Frame 070491/0243 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 7, 2021
From: MATZA, STEPHEN D.
To: UNITED LABORATORIES INTERNATIONAL, LLC
Reel/Frame 057400/0897 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: MATZA, STEPHEN D.
To: UNITED LABORATORIES INTERNATIONAL, LLC
Reel/Frame 039019/0885 →