COMPOSITIONS INCORPORATING DIELECTRIC ADDITIVES FOR PARTICLE FORMATION, AND METHODS OF PARTICLE FORMATION USING SAME
A method of forming particles that includes performing a strong force attenuation of a mixture to form pre-particles. The mixture including a base compound and a dielectric additive having an elevated dielectric constant dispersed therein. The pre-particles are then dielectrically spun in an electrostatic field to further attenuate the pre-particles and form the particles.
1 .- 9 . (canceled)
10 . A composition for particle formation, comprising:
a base compound; and
a dielectric additive selected to encourage dielectrophoretic attenuation of the base compound during dielectric spinning.
11 . The composition of claim 10 , wherein the dielectric additive includes a mild dielectric additive having a dielectric constant above 5.
12 . The composition of claim 10 , wherein the dielectric additive includes a moderate dielectric additive having a dielectric constant above 10
13 . The composition of claim 10 , wherein the dielectric additive includes a strong dielectric additive having a dielectric constant above 100.
14 . The composition of claim 10 , wherein the dielectric additive includes polyglycerol-3.
15 . The composition of claim 10 , wherein the dielectric additive includes titanium dioxide (TiO 2 ).
16 . The composition of claim 10 , wherein the dielectric additive includes barium titanate.
17 . The composition of claim 10 , wherein the dielectric additive includes a ceramic dielectric.
18 . The composition of claim 10 , wherein the dielectric additive includes high-relative permittivity nanoparticles dispersed within the base compound.
19 . The composition of claim 10 , further comprising a dispersant selected to aid in dispersing the dielectric additive within the base compound.
20 . The composition of claim 19 , wherein the dispersant includes sodium stearate.
21 . The composition of claim 19 , wherein the dispersant includes sodium oleate.
22 . The composition of claim 19 , wherein the dispersant includes stearic acid.
23 . The composition of claim 10 , further comprising a viscosity-reduction additive selected to reduce the viscosity of the base compound.
24 . The composition of claim 23 , wherein the viscosity-reduction additive includes Irgatec CR-76.
25 . The composition of claim 23 , wherein the viscosity-reduction additive includes peroxide.
26 . The composition of claim 10 , further comprising a conductivity additive.
27 . The composition of claim 10 , further comprising an ionic liquid.
28 . The composition of claim 27 , wherein the ionic liquid is mixed with the dielectric additive.
29 . The composition of claim 10 , wherein a conductive additive is mixed with the dielectric additive.
30 . The composition of claim 10 , wherein the composition is substantially solvent-free.
31 . The composition of claim 10 , comprising 85 to 99% by weight base compound, and 0.5 to 20% by weight dielectric additive.
32 . The composition of claim 10 , comprising 0 to 5% by weight dispersant.
33 . The composition of claim 10 , comprising 0 to 10% by weight viscosity-reduction additive.
34 . The composition of claim 10 , wherein the base compound is a polymer.
35 . The composition of claim 34 , wherein the polymer is a thermoplastic polymer.
36 . The composition of claim 10 , wherein the base compound is selected from a group consisting of:
a. polyethylene;
b. polypropylene;
c. polycaprolactone;
d. co-polymers of polyethylene-acrylic acid
e. polyacrylonitrile;
f. polyamides;
g. polybutadiene;
h. polycarbonate;
i. polychloroprene;
j. polychlorotrifluoroethylene;
k. poly(ethylene terephthalate);
l. polyisoprene;
m. poly(methyl methacrylate);
n. polyoxymethylene;
o. poly(phenylene oxide);
p. polystyrene;
q. polysulfones;
r. polytetrafluoroethylene;
s. poly(vinyl acetate);
t. poly(vinyl chloride);
u. polyester;
v. wax;
w. polypyrrole;
x. polyaniline;
y. poly(vinylidene chloride);
z. poly(vinylidene fluoride);
aa. co-polymers; and
bb. blends.
37 . The composition of claim 10 , wherein the base compound is selected from the group consisting of:
a. liquid polymers;
b. molten glasses;
c. molten metals;
d. molten salts;
e. minerals;
f. ceramics;
g. pure liquid substances;
h. suspensions;
i. emulsions;
j. colloids;
k. latex;
l. solutions; and
m. mixtures.
38 . The composition of claim 19 , wherein the dispersant is selected from the group consisting of:
a. sodium stearate; and
b. sodium oleate.
39 . The composition of claim 10 , wherein the dielectric additive is selected from the group consisting of:
a. polyglycol;
b. glycol;
c. mannitol;
d. ionic liquid;
e. polycaprolactone;
f. polyglycerol;
g. glycerol;
h. titanium dioxide; and
i. barium titanate.
40 . The composition of claim 10 , wherein the viscosity-reduction additive is selected from the group consisting of:
a. Irgatec CR-76;
b. peroxides;
c. waxes; and
d. lubricants.
41 .- 60 . (canceled)