Deposition approaches for emitter layers of solar cells
View Patent ↗Methods of fabricating solar cells, and the resulting solar cells, are described herein. In an example, a method of fabricating a solar cell includes forming a thin dielectric layer on a surface of a substrate by radical oxidation or plasma oxidation of the surface of the substrate. The method also involves forming a silicon layer over the thin dielectric layer. The method also involves forming a plurality of emitter regions from the silicon layer.
1. A method of fabricating a solar cell, the method comprising:
forming a thin dielectric layer on a surface of a substrate by radical oxidation or plasma oxidation of the surface of the substrate;
forming a first silicon layer over the thin dielectric layer;
patterning the first silicon layer, the thin dielectric layer, and a portion of the substrate to form a first emitter region from the first silicon layer, the first emitter region adjacent a trench; and
forming a second silicon layer in the trench and over a portion of the first emitter region to form a second emitter region adjacent the first emitter region.
2. The method of claim 1 , further comprising:
prior to forming the thin dielectric layer, dry cleaning the surface of the substrate to remove metal or organic contaminants.
3. The method of claim 2 , wherein dry cleaning the surface of the substrate comprises dry cleaning in a plasma enhanced chemical vapor deposition (PECVD) chamber.
4. The method of claim 1 , wherein forming the thin dielectric layer on the surface of the substrate comprises forming the thin dielectric layer in a plasma enhanced chemical vapor deposition (PECVD) chamber.
5. The method of claim 1 , wherein forming the first silicon layer comprises forming the first silicon layer in a plasma enhanced chemical vapor deposition (PECVD) chamber.
6. The method of claim 5 , wherein forming the thin dielectric layer on the surface of the substrate comprises forming the thin dielectric layer in the PECVD chamber.
7. The method of claim 6 , further comprising:
prior to forming the thin dielectric layer, dry cleaning the surface of the substrate to remove metal or organic contaminants, the dry cleaning performed in the PECVD chamber.
8. The method of claim 1 , wherein forming the first emitter region from the first silicon layer comprises doping the first silicon layer in an implant chamber housed in a tool that also houses a plasma enhanced chemical vapor deposition (PECVD) chamber used to form the thin dielectric layer or the first silicon layer, or both.
9. The method of claim 1 , further comprising:
forming conductive contacts electrically connected to the first and second emitter regions.
10. The method of claim 1 , wherein forming the thin dielectric layer on the surface of the substrate comprises forming the thin dielectric layer by radical oxidation.
11. The method of claim 1 , wherein forming the thin dielectric layer on the surface of the substrate comprises forming the thin dielectric layer by plasma oxidation.
12. A method of fabricating a solar cell, the method comprising:
forming a first thin dielectric layer on a surface of a substrate;
forming a first silicon layer over the first thin dielectric layer;
patterning the first silicon layer, the first thin dielectric layer, and a portion of the substrate to form a first emitter region from the first silicon layer, the first emitter region adjacent a trench;
forming a second thin dielectric layer on sidewalls of the patterned first silicon layer by radical oxidation or plasma oxidation of the surface of sidewalls of the patterned first silicon layer; and
forming a second silicon layer in the trench and over a portion of the first emitter region to form a second emitter region adjacent the first emitter region, wherein the second thin dielectric layer laterally electrically isolates the first emitter region from the second emitter region.
13. The method of claim 12 , wherein forming the second thin dielectric layer on sidewalls of the patterned first silicon layer comprises forming the second thin dielectric layer in a plasma enhanced chemical vapor deposition (PECVD) chamber.
14. The method of claim 1 , wherein forming the second silicon layer comprises forming the second silicon layer in a plasma enhanced chemical vapor deposition (PECVD) chamber.
15. The method of claim 14 , wherein forming the second thin dielectric layer on sidewalls of the patterned first silicon layer comprises forming the thin dielectric layer in the PECVD chamber.
16. The method of claim 12 , wherein forming the second emitter region from the second silicon layer comprises doping the second silicon layer in an implant chamber housed in a tool that also houses a plasma enhanced chemical vapor deposition (PECVD) chamber used to form the second thin dielectric layer or the second silicon layer, or both.
17. The method of claim 12 , further comprising:
forming conductive contacts electrically connected to the first and second emitter regions.
18. The method of claim 12 , wherein forming the second thin dielectric layer on sidewalls of the patterned first silicon layer comprises forming the second thin dielectric layer by radical oxidation.
19. The method of claim 12 , wherein forming the second thin dielectric layer on sidewalls of the patterned first silicon layer comprises forming the second thin dielectric layer by plasma oxidation.