Coatings for metal interconnects to reduce SOFC degradation
View Patent ↗A method of coating an interconnect for a solid oxide fuel cell includes providing an interconnect including Cr and Fe, and coating an air side of the interconnect with a manganese cobalt oxide spinel coating using a plasma spray process.
1. A coated interconnect for a solid oxide fuel cell, comprising:
an interconnect substrate comprising iron and chromium;
a single layer composite coating disposed on an air side of the interconnect substrate, the coating comprising a strontium-doped lanthanum manganate perovskite phase matrix and a manganese cobalt oxide spinel phase disposed in the matrix as discrete plate-shaped regions; and
an intermediate layer disposed between the composite coating and the interconnect substrate, the intermediate layer comprising a (Mn, Cr, Co) 3 O 4 spinel phase formed during in-stack conditioning by a reaction between the interconnect substrate and the composite layer,
wherein the composite coating is formed using a plasma spray process and the composite coating is not a bilayer of perovskite and spinel.
2. The interconnect of claim 1 , wherein the composite coating is formed using an air plasma spray process.
3. The interconnect of claim 1 , wherein a weight ratio of the matrix to the spinel phase is between 20:80 and 90:10.
4. The interconnect of claim 3 , wherein the weight ratio of the matrix to the spinel phase is between 50:50 and 80:20.
5. The interconnect of claim 3 , wherein the spinel phase comprises Mn 2−x Co 1+x O 4 , where 0≤x≤1.
6. The interconnect of claim 3 , wherein the atomic ratio of Co to Mn in the spinel phase is at least 1:3.
7. The interconnect of claim 6 , wherein the atomic ratio of Co to Mn in the spinel phase is between 1:3 and 6:4.
8. The interconnect of claim 3 , wherein the spinel phase further comprises at least one of Cu and one or more single valence elements selected from the group consisting of Y 3+ , Al 3+ , Mg 2+ and Zn 2+ .
9. The interconnect of claim 3 , wherein the composite coating further comprises a getter comprising at least one of Al 2 O 3 , Y 2 O 3 , and TiO 2 .
10. The interconnect of claim 3 , wherein:
the matrix comprises La 1−x Sr x MnO 3 , where 0.1≤x≤0.3; and
the interconnect substrate comprises a chromium-iron alloy containing 92 to 97 weight percent chromium, 3 to 7 weight percent iron, and 0 to 1 weight percent of yttrium or yttria.