Method of making hydrophobic coated article, coated article including hydrophobic coatings, and/or sol compositions for use in the same
View Patent ↗Certain example embodiments relate to a coated article including a coating formed from a sol that has hydrophobic surface properties. The sol may include a mixture of at least two alkylsiloxane chemicals, with the sol potentially being aged for a certain comparatively short amount of time before being wet-applied to a major substrate surface. The application process may also undergo a certain comparatively short curing process to help provide hydrophobic surface properties. The hydrophobic surface properties help provide anti-soiling functions that are advantageous in a variety of applications including, for example, solar mirror applications.
1. A method of making a coated article comprising a glass substrate supporting a coating, the method comprising:
applying a sol on a major surface of the substrate, the sol comprising at least first and second alkylsiloxane chemicals and a plurality of silica nanoparticles, the first alkylsiloxane chemical comprising tetraethyl orthosilicate and the second alkylsiloxane chemical comprising a siloxane other than tetraethyl orthosilicate, wherein the tetraethyl orthosilicate and the second alkylsiloxane chemical comprising a siloxane other than tetraethyl orthosilicate are provided in weight percentages in the sol that differ from one another by no more than 5%; and
drying and/or curing the sol to form the coating, the coating having a root mean square roughness of 3-6.5 nm.
2. The method of claim 1 , wherein the sol is aged for less than or equal to 1 month prior to applying.
3. The method of claim 1 , wherein alkylsiloxane chains protrude outwardly from a surface of the coating.
4. The method of claim 1 , wherein alkylsiloxane groups are hydrolyzed using an acid catalysis process.
5. The method of claim 1 , wherein the first and second alkylsiloxane chemicals are provided at substantially equal weight percentages.
6. The method of claim 1 , wherein the coating has a refractive index below 1.3.
7. The method of claim 6 , wherein the coating is hydrophobic.
8. The method of claim 6 , wherein the coating has a water contact angle theta greater than about 100 degrees.
9. The method of claim 1 , wherein the coating has a water contact angle theta of greater than about 100 degrees.
10. The method of claim 1 , wherein the coating is cured for less than 15 minutes.
11. The method of claim 1 , wherein the second alkylsiloxane chemical comprises octyltrimethoxysiloxane, pentyltriethoxysiloxane, 3,3,3-trifluoropropyl trimethoxysiloxane, or a combination thereof.
12. The method of claim 1 , wherein the sol is aged from 1 month to 5 months prior to applying.
13. The method of claim 12 , wherein the coating has a water contact angle theta greater than about 100 degrees.
14. The method of claim 1 , wherein the sol is aged for no more than five months prior to applying.
15. The method of claim 1 , wherein the sol is applied directly on the major surface of the substrate.
16. A method of making a coated article comprising a glass substrate supporting a coating, the method comprising:
applying a sol on a major surface of the substrate, the sol comprising at least first and second alkylsiloxane chemicals and a solvent comprising an alcohol, the first alkylsiloxane chemical comprising tetraethyl orthosilicate and the second alkylsiloxane chemical comprising a siloxane other than tetraethyl orthosilicate, wherein the tetraethyl orthosilicate and the second alkylsiloxane chemical comprising a siloxane other than tetraethyl orthosilicate are provided in weight percentages in the sol that differ from one another by no more than 5%; and
drying and/or curing the sol to form the coating, the coating having a root mean square roughness of 3-6.5 nm.