Methods of cleaning and/or neutralizing an at least partially leached polycrystalline diamond body and resulting polycrystalline diamond compacts
Embodiments relate to polycrystalline diamond compacts (“PDCs”), methods of fabricating PDCs, and applications for such PDCs. In an embodiment, a method includes providing an at least partially leached polycrystalline diamond (“PCD”) body. A residual amount of acid may remain in and/or on the at least partially leached PCD body. The method further includes removing and/or neutralizing at least some of the residual amount of acid from the at least partially leached PCD body and/or a substrate to which the at least partially leached PCD body is attached.
1. A method, comprising:
providing a polycrystalline diamond body including a plurality of diamond grains defining a plurality of interstitial regions having at least one interstitial material occupying at least a portion of the plurality of interstitial regions;
at least partially leaching at least some of the at least one interstitial material from the polycrystalline diamond body to form an at least partially leached polycrystalline diamond body including a residual amount of acid; and
neutralizing at least a portion of the residual amount of acid by exposing the polycrystalline diamond body to at least one of a powdered base material and a flow of a gaseous base.
2. The method of claim 1 , wherein the residual amount of acid includes at least one of hydrochloric acid, nitric acid, phosphoric acid, acetic acid, or hydrofluoric acid.
3. The method of claim 1 , further comprising removing and/or neutralizing an additional portion of the residual amount of acid from the polycrystalline diamond body by heating the at least partially leached polycrystalline diamond body.
4. The method of claim 3 , further comprising rinsing the at least partially leached polycrystalline diamond body before and/or after heating the at least partially leached polycrystalline diamond body.
5. The method of claim 3 , wherein heating the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body to a temperature about 100° C. to about 700° C.
6. The method of claim 3 , wherein heating the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body to a temperature about 150° C. to about 400° C.
7. The method of claim 3 , wherein heating the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body to a temperature about 250° C. to about 400° C.
8. The method of claim 3 , wherein heating the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body for a time period about 20 minutes to about 240 minutes.
9. The method of claim 3 , wherein heating the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body at a selected temperature and for a selected duration, wherein the selected temperature and the selected duration is determined at least partially based on at least one of diamond particle size used to form the polycrystalline diamond body, diamond grain size distribution of the polycrystalline diamond body, amount of diamond-to-diamond bonding in the at least partially leached polycrystalline diamond body, porosity of the at least partially leached polycrystalline diamond body, average pore size of the at least partially leached polycrystalline diamond body, type of at least one interstitial material leached, leach time, leach depth, type of acid used to leach the at least partially leached polycrystalline diamond body, desired pH of the at least partially leached polycrystalline diamond body, or desired anion concentration in the at least partially leached polycrystalline diamond body.
10. The method of claim 3 , wherein heating the at least partially leached polycrystalline diamond body includes heating the at least partially leached polycrystalline diamond body by exposing the at least partially leached polycrystalline diamond body to a temperature that varies.
11. The method of claim 1 , further comprising removing and/or neutralizing an additional portion of the residual amount of acid by heating the at least partially leached polycrystalline diamond body in an autoclave.
12. The method of claim 11 , wherein heating the at least partially leached polycrystalline diamond body in the autoclave includes heating the at least partially leached polycrystalline diamond body in the autoclave at a temperature about 120° C. to about 230° C.
13. The method of claim 11 , wherein heating the at least partially leached polycrystalline diamond body in the autoclave includes heating the at least partially leached polycrystalline diamond body in the autoclave for a time period about 1 hour to about 4 hours.
14. The method of claim 1 , further comprising removing and/or neutralizing an additional portion of the residual amount of acid by exposing the at least partially leached polycrystalline diamond body to a vacuum.
15. The method of claim 14 , further comprising heating the at least partially leached polycrystalline diamond body while exposing the at least partially leached polycrystalline diamond body to the vacuum.
16. The method of claim 1 , wherein the at least partially leached polycrystalline diamond body is bonded to a substrate prior to neutralizing at least the portion of the residual amount of acid.
17. The method of claim 1 , wherein the polycrystalline diamond body exhibits a pH of about 5 to about 9 following neutralization of at least the portion of the residual amount of acid with the base.
18. The method of claim 1 , wherein the at least one interstitial material includes a at least one of a metal-solvent catalyst or a metallic infiltrant.
19. The method of claim 1 , wherein neutralizing at least the portion of the residual amount of acid further comprises enclosing the polycrystalline diamond body in the powdered base material.
20. The method of claim 1 , wherein the powdered base material comprises at least one of sodium bicarbonate and calcium carbonate.
21. The method of claim 1 , wherein providing the polycrystalline diamond body comprises providing the polycrystalline diamond body bonded to a cemented tungsten carbide substrate.
22. A method, comprising:
providing a polycrystalline diamond compact including:
a substrate; and
a polycrystalline diamond body bonded to the substrate, the polycrystalline diamond body including a plurality of diamond grains defining a plurality of interstitial regions having at least one interstitial material occupying at least a portion of the plurality of interstitial regions;
at least partially leaching at least some of the at least one interstitial material from the polycrystalline diamond body to form an at least partially leached polycrystalline diamond body including a residual amount of acid; and
neutralizing at least a portion of the residual amount of acid by exposing the polycrystalline diamond body to at least one of a powdered base material and a flow of a gaseous base.