Multilayer thermoplastic film
A thermoplastic polymer advanceable by solid state polymerization is blended with at least one dissimilar thermoplastic polymer. The blend is solid state polymerized to provide a modified polymer alloy blend having at least one physical or chemical property different from that of the blend before solid state polymerization. The modified polymer alloy blend may be coextruded with a layer of thermoplastic extrusion polymer having a melt viscosity similar to that of the modified polymer alloy.
1. A multilayer film comprising:
a first polymeric layer defining a first melt viscosity; and
a second polymeric layer, wherein the second polymeric layer is directly adjacent to and coextruded with the first polymeric layer to form a freestanding self-supporting film,
wherein the first and second polymeric layers are different, and
wherein the second polymeric layer comprises a modified polymer alloy to provide the second polymeric layer with a second melt viscosity within about ±15% of the first melt viscosity of the first polymeric layer at an extrusion temperature selected within a temperature range of about 200-300° C. and a shear rate selected within a shear rate range of about 50-500 l/s,
wherein the modified polymer alloy comprises a thermoplastic polymer and at least one dissimilar polymer, wherein at least the thermoplastic polymer is advanceable by solid state polymerization and comprises one or more:
condensation polymers selected from polyesters, copolyesters, polyamides, polycarbonates, and combinations thereof;
addition polymers selected from polylactones, polymethyl methacrylate (PMMA), styrene/maleic anhydride (SMA), polyurethanes, and combinations thereof; or
an advanceable polymer selected from polyoxymethylene (POM), polyketones, thermoplastic fluoropolymers, polyphenylene oxide (PPO), imide polymers, sulfone polymer's polyaminoacids, polydimethylsiloxanes, and combinations thereof, and
wherein the thermoplastic polymer has been blended with the dissimilar polymer, and the blend has been solid state polymerized to have a melt viscosity greater than that of the blend before solid state polymerization.
2. The multilayer film according to claim 1 wherein the thermoplastic polymer comprises a condensation polymer.
3. The multilayer film according to claim 1 wherein the thermoplastic polymer comprises an alkyd polyester or an alkyd copolyester.
4. The multilayer film according to claim 1 wherein the thermoplastic polymer comprises a polyester.
5. The multilayer film according to claim 1 wherein the thermoplastic polymer comprises a polyester and the dissimilar polymer comprises a copolyester.
6. The multilayer film according to claim 1 wherein all layers of the multilayer film have a melt viscosity within about ±15% of the modified polymer alloy melt viscosity at an extrusion temperature selected within a temperature range of about 200-300° C. and a shear rate selected within a shear rate range of about 50-500 l/s.
7. The multilayer film according to claim 1 wherein all layers of the multilayer film have a melt viscosity within about ±10% of the modified polymer alloy melt viscosity at an extrusion temperature selected within a temperature range of about 200-300° C. and a shear rate selected within a shear rate range of about 50-500 l/s.
8. The multilayer film according to claim 1 wherein all layers of the multilayer film have a melt viscosity within about ±5% of the modified polymer alloy melt viscosity at an extrusion temperature selected within a temperature range of about 200-300° C. and a shear rate selected within a shear rate range of about 50-500 l/s.
9. The multilayer film according to claim 1 wherein the thermoplastic polymer comprises a polyester homopolymer.
10. The multilayer film according to claim 1 wherein the thermoplastic polymer comprises polyethylene terephthalate.
11. The multilayer film according to claim 1 wherein the dissimilar polymer comprises a condensation polymer.
12. The multilayer film according to claim 1 wherein the thermoplastic polymer and dissimilar polymer both comprise condensation polymers.
13. The multilayer film according to claim 1 wherein the dissimilar polymer is advanceable by solid state polymerization.
14. The multilayer film according to claim 1 wherein the dissimilar polymer is not advanceable by solid state polymerization.
15. The multilayer film according to claim 1 wherein the dissimilar polymer has a Tg that on an absolute scale differs from that of the thermoplastic polymer by ±5% or more.
16. The multilayer film according to claim 1 wherein the first polymeric layer contains polyethylene terephthalate, the second polymeric layer contains polyethylene terephthalate and a copolyester, and
wherein the multilayer film further comprises a third polymeric layer containing polyethylene terephthalate and a copolyester and directly adjacent to and coextruded with the first polymeric layer, the third polymeric layer having a third melt viscosity within about ±15% of the first melt viscosity of the first polymeric layer at an extrusion temperature selected within a temperature range of about 200-300° C. and a shear rate selected within a shear rate range of about 50-500 l/s.
17. The multilayer film according to claim 1 wherein the modified polymer alloy contains rearranged blocks or segments of the thermoplastic polymer and dissimilar polymer.
18. The multilayer film according to claim 1 wherein the film contains recycled polyethylene terephthalate.
19. The multilayer film according to claim 1 wherein the film contains virgin and recycled polyethylene terephthalates.
20. The multilayer film according to claim 1 wherein the modified polymer alloy contains a blend of from about 99 to about 1 weight percent of the thermoplastic polymer and from about 1 to about 99 weight percent of the at least one dissimilar polymer.
21. The multilayer film according to claim 1 wherein the modified polymer alloy contains a blend of from about 95 to about 5 weight percent of the thermoplastic polymer and from about 5 to about 95 weight percent of the at least one dissimilar polymer.
22. The multilayer film according to claim 1 wherein the modified polymer alloy contains a blend of from about 90 to about 10 weight percent of the thermoplastic polymer and from about 10 to about 90 weight percent of the at least one dissimilar polymer.
23. A process for forming a multilayer film comprising:
a) providing a first thermoplastic polymer used to form a first polymeric layer defining a first melt viscosity at a chosen extrusion temperature selected within a temperature range of about 200-300° C. and a chosen shear rate selected within a shear rate range of about 50-500 l/s;
b) providing a second thermoplastic polymer advanceable by solid state polymerization and comprising:
condensation polymers selected from polyesters, copolyesters, polyamides, polycarbonates, and combinations thereof;
addition polymers selected from polylactones, polymethyl methacrylate (PMMA), styrene/maleic anhydride (SMA), polyurethanes, and combinations thereof; or
an advanceable polymer selected from polyoxymethylene (POM), polyketones, thermoplastic fluoropolymers, polyphenylene oxide (PPO), imide polymers, sulfone polymer's polyaminoacids, polydimethylsiloxanes, and combinations thereof;
c) blending the second thermoplastic polymer with at least one dissimilar polymer;
d) solid state polymerizing the blended second thermoplastic polymer and at least one dissimilar polymer to form a modified polymer alloy having a second melt viscosity greater than that of the blend before solid state polymerization and within about ±15% of the first melt viscosity at the chosen extrusion temperature and chosen shear rate;
e) coextruding a layer of the modified polymer alloy and a layer of the first thermoplastic polymer directly adjacent to one another to form the first polymeric layer having the first melt viscosity and a second polymeric layer having the second melt viscosity; and
f) cooling the coextruded layers to form a freestanding, self-supporting multilayer film.