IP Library Granted Patent US 9,776,908
Granted Patent B2
US 9,776,908 · App. 14/885,017 · Granted Oct 3, 2017

Coating film-attached glass, coating film-attached chemically strengthened glass, exterior member, and electronic device

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Quick Facts
Patent No.
US 9,776,908
App. No.
14/885,017
Granted
Oct 3, 2017
Kind
B2
Abstract

Coating film-attached glass includes: glass containing a coloring component; and a colored coating film formed on one major surface of the glass, wherein at least one of an absolute value of a difference between (Δa*(D65−F2)) of the glass and (Δa*(D65−F2)) of the coating film and an absolute value of a difference between (Δa*(A−F2)) of the glass and (Δa*(A−F2)) of the coating film is 0.2 or more, where (Δa*(D65−F2)) is a difference between a chromaticity a* value of reflected light by a D65 light source and a chromaticity a* value of reflected light by an F2 light source in an L*a*b* color system and (Δa*(A−F2)) is a difference between a chromaticity a* value of reflected light by an A light source and the chromaticity a* value of the reflected light by the F2 light source in the L*a*b* color system.

Claims (32)

1. A coating film-attached glass comprising, glass containing a coloring component; and a colored coating film formed on one major surface of the glass,

wherein at least one of an absolute value of a difference between (Δa*(D65−F2)) of the glass and (Δa*(D65−F2)) of the coating film and an absolute value of a difference between (Δa*(A−F2)) of the glass and (Δa*(A−F2)) of the coating film is 0.2 or more,

where (Δa*(D65−F2)) is a difference between a chromaticity a* value of reflected light by a D65 light source and a chromaticity a* value of reflected light by an F2 light source in an L*a*b* color system, which difference is expressed by the following expression (1),

Δ a *( D 65− F 2)= a *value( D 65 light source)− a *value( F 2 light source)  (1), and

(Δa*(A−F2)) is a difference between a chromaticity a* value of reflected light by an A light source and the chromaticity a* value of the reflected light by the F2 light source in the L*a*b* color system, which difference is expressed by the following expression (2),

Δ a *( A−F 2)= a *value( A light source)− a *value( F 2 light source)  (2),

values calculated by the expression (1) and the expression (2) are values of chromaticities of the major surface which are measured on the glass in a state of a glass plate with a 0.8 mm thickness, and values of chromaticities which are measured on the coating film in a state being formed on a transparent substrate.

2. The coating film-attached glass according to claim 1 ,

wherein an L* value (F2 light source) of the glass in the L*a*b* color system is within a range of 20 to 90.

3. The coating film-attached glass according to claim 1 ,

wherein the glass contains, in terms of molar percentage on a basis of the following oxides, 55 to 80% of SiO 2 , 0.25 to 16% of Al 2 O 3 , 0 to 12% of B 2 O 3 , 5 to 20% of Na 2 O, 0 to 15% of K 2 O, 0 to 15% of MgO, 0 to 15% of CaO, 0 to 25% of ΣRO (R is Mg, Ca, Sr, Ba, Zn), and 0.001 to 10% of MpOq (M is at least one kind selected from Fe, Cu, V, Se, Co, Ti, Cr, Pr, Ce, Bi, Eu, Mn, Er, Ni, Nd, W, Rb, and Ag, and p and q are atomic ratios of M and O).

4. The coating film-attached glass according to claim 1 , being used as an exterior member.

5. An exterior member comprising the coating film-attached glass according to claim 1 .

6. An electronic device comprising the exterior member according to claim 5 provided on an exterior of the electronic device.

7. Coating film-attached chemically strengthened glass being coating film-attached glass comprising: glass containing a coloring component; and a colored coating film formed on one major surface of the glass,

wherein:

at least one of an absolute value of a difference between (Δa*(D65−F2)) of the glass and (Δa*(D65−F2)) of the coating film and an absolute value of a difference between (Δa*(A−F2)) of the glass and (Δa*(A−F2)) of the coating film is 0.2 or more;

where (Δa*(D65−F2)) is a difference between a chromaticity a* value of reflected light by a D65 light source and a chromaticity a* value of reflected light by an F2 light source in an L*a*b* color system, which difference is expressed by the following expression (1),

Δ a *( D 65− F 2)= a *value( D 65 light source)− a *value( F 2 light source)  (1), and

(Δa*(A−F2)) is a difference between a chromaticity a* value of reflected light by an A light source and the chromaticity a* value of the reflected light by the F2 light source in the L*a*b* color system, which difference is expressed by the following expression (2),

Δ a *( A−F 2)= a *value( A light source)− a *value( F 2 light source)  (2),

values calculated by the expression (1) and the expression (2) are values of chromaticities of the major surface which are measured on the glass in a state of a glass plate with a 0.8 mm thickness, and values of chromaticities which are measured on the coating film in a state of being formed on a transparent substrate; and

the glass is chemically strengthened glass having a surface compressive stress layer with 5 to 70 μm from a surface of the glass in a depth direction.

8. The coating film-attached chemically strengthened glass according to claim 7 ,

wherein an L* value (F2 light source) of the glass in the L*a*b* color system is within a range of 20 to 90.

9. The coating film-attached chemically strengthened glass according to claim 7 ,

wherein the glass contains, in terms of molar percentage on a basis of the following oxides, 55 to 80% of SiO 2 , 0.25 to 16% of Al 2 O 3 , 0 to 12% of B 2 O 3 , 5 to 20% of Na 2 O, 0 to 15% of K 2 O, 0 to 15% of MgO, 0 to 15% of CaO, 0 to 25% of ΣRO (R is Mg, Ca, Sr, Ba, Zn), and 0.001 to 10% of MpOq (M is at least one kind selected from Fe, Cu, V, Se, Co, Ti, Cr, Pr, Ce, Bi, Eu, Mn, Er, Ni, Nd, W, Rb, and Ag, and p and q are atomic ratios of M and O).

10. The coating film-attached chemically strengthened glass according to claim 7 ,

wherein the glass has a 300 to 1400 MPa surface compressive stress.

11. The coating film-attached chemically strengthened glass according to claim 7 , being used as an exterior member.

12. An exterior member comprising the coating film-attached chemically strengthened glass according to claim 7 .

13. An electronic device comprising the exterior member according to claim 12 provided on an exterior of the electronic device.

Assignments (2)
CHANGE OF NAME Recorded Aug 7, 2018
From: ASAHI GLASS COMPANY, LIMITED
To: AGC INC.
Reel/Frame 046730/0786 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 16, 2015
From: YAMAMOTO, HIROYUKI; KUNO, KAZUHIDE; SHIRATORI, MAKOTO
To: ASAHI GLASS COMPANY, LIMITED
Reel/Frame 036808/0850 →