Fuel cell interconnect
View Patent ↗Methods for fabricating an interconnect for a fuel cell stack include placing a compressed metal powder interconnect on a porous support, and sintering the interconnect in the presence of a non-oxidizing gas. The method may further include placing the sintered interconnect on a porous support, and oxidizing the interconnect in the presence of flowing air, or placing the sintered interconnect on a dense, non-porous support, and oxidizing the interconnect in the presence of a gas comprising pure oxygen or an oxygen/inert gas mixture that is substantially nitrogen-free.
1. An interconnect for a solid oxide fuel cell stack, comprising:
a first plurality of ribs extending from a first major surface of the interconnect and defining a first plurality of gas flow channels between the ribs, the ribs extending between a first rib end and a second rib end and having a convex rounded upper surface over a first portion of the ribs that provides a tapered profile in a vertical dimension, perpendicular to the first major surface of the interconnect, proximate at least one of the first rib end and the second rib end,
wherein the ribs comprise a flat upper surface over a second portion of the ribs and rounded edges between the flat upper surface and the adjacent gas flow channels, the rounded edges having a first radius of curvature,
wherein the gas flow channels comprise a rounded surface having a second radius of curvature, different from the first radius of curvature, and
wherein the interconnect is formed of a pressed metal powder, and
wherein the gas flow channels comprise a continuously rounded surface having a semi-circular cross section.
2. The interconnect of claim 1 , wherein the ribs further have a tapered profile in a horizontal dimension, parallel to the first major surface of the interconnect, proximate at least one of the first rib end and the second rib end.
3. The interconnect of claim 1 , further comprising a second plurality of ribs extending from a second major surface of the interconnect, opposite the first major surface, and defining a second plurality of gas flow channels between the second plurality of ribs, the second plurality of ribs extending between a first rib end and a second rib end and having a convex rounded upper surface over a first portion of the ribs that provides a tapered profile in a vertical dimension, perpendicular to the second major surface of the interconnect, proximate at least one of the first rib end and the second rib end,
wherein the second plurality of ribs comprise a flat upper surface over a second portion of the ribs and rounded edges between the flat upper surface and the adjacent gas flow channels, the rounded edges having a third radius of curvature; and
wherein the second plurality of gas flow channels comprise a rounded surface having a fourth radius of curvature, different from the third radius of curvature.
4. The interconnect of claim 3 , wherein the second plurality of ribs and the second plurality of gas flow channels are offset relative to the first plurality of ribs and the first plurality of gas flow channels respectively.
5. The interconnect of claim 3 , wherein the first radius of curvature and the third radius of curvature are the same and the second radius of curvature and the fourth radius of curvature are the same.
6. The interconnect of claim 1 , wherein the interconnect is formed by pressing the metal powder in a single pressing step to near net shape or to net shape.
7. The interconnect of claim 1 , wherein the interconnect has an iron content of between 3-7% by weight.
8. The interconnect of claim 1 , further comprising:
a riser channel opening for a gas extending through the interconnect; and
a plenum for collecting the gas on a first major surface of the interconnect, wherein the plenum extends at least about 60% around the circumference of the riser channel opening.
9. A method of fabricating an interconnect for a solid oxide fuel cell stack, comprising:
pressing a metal powder to form a interconnect having a first plurality of ribs extending from a first major surface of the interconnect and defining a first plurality of gas flow channels between the ribs, the ribs extending between a first rib end and a second rib end and having a convex rounded upper surface over a first portion of the ribs that provides a tapered profile in a vertical dimension, perpendicular to the first major surface of the interconnect, proximate at least one of the first rib end and the second rib end,
wherein the ribs comprise a flat upper surface over a second portion of the ribs and rounded edges between the flat upper surface and the adjacent gas flow channels, the rounded edges having a first radius of curvature,
wherein the gas flow channels comprise a rounded surface having a second radius of curvature, different from the first radius of curvature, and
wherein the gas flow channels comprise a continuously rounded surface having a semi-circular cross section.
10. The method of claim 9 , wherein the first radius of curvature is smaller than the second radius of curvature.
11. The method of claim 9 , wherein the ribs further have a tapered profile in a horizontal dimension, parallel to the first major surface of the interconnect, proximate at least one of the first rib end and the second rib end.
12. The method of claim 9 , wherein pressing the metal powder forms an interconnect having a second plurality of ribs extending from a second major surface of the interconnect, opposite the first major surface, and defining a second plurality of gas flow channels between the second plurality of ribs, the second plurality of ribs extending between a first rib end and a second rib end and having a convex rounded upper surface over a first portion of the ribs that provides a tapered profile in a vertical dimension, perpendicular to the second major surface of the interconnect, proximate at least one of the first rib end and the second rib end,
wherein the second plurality of ribs comprise a flat upper surface over a second portion of the ribs and rounded edges between the flat upper surface and the adjacent gas flow channels, the rounded edges having a third radius of curvature; and
wherein the second plurality of gas flow channels comprise a rounded surface having a fourth radius of curvature, different from the third radius of curvature.
13. The method of claim 12 , wherein the second plurality of ribs and the second plurality of gas flow channels are offset relative to the first plurality of ribs and the first plurality of gas flow channels respectively.
14. The method of claim 9 , wherein pressing the metal powder comprises pressing the powder in a single pressing step to near net shape or net shape to form the interconnect.
15. The method of claim 9 , further comprising:
sintering the pressed powder interconnect.
16. The method of claim 9 , further comprising:
incorporating the interconnect into a solid-oxide fuel cell (SOFC) stack.
17. The method of claim 9 , wherein the metal powder comprises chromium and iron powders having an iron content of at between 3-7% by weight.
18. The method of claim 9 , wherein pressing the metal powder to form an interconnect comprises forming the interconnect with a riser channel opening for a gas extending through the interconnect and a plenum for collecting the gas on a first major surface of the interconnect, wherein the plenum extends at least about 60% around the circumference of the riser channel opening.
19. An interconnect for a solid oxide fuel cell stack, comprising:
a first plurality of ribs extending from a first major surface of the interconnect and defining a first plurality of gas flow channels between the ribs, wherein
the gas flow channels comprise a continuously rounded surface, and
the interconnect is formed of a pressed metal powder.
20. The interconnect of claim 19 , wherein the gas flow channels comprise a continuously rounded surface having a semi-circular cross section.