Method of purifying yttrium
A method of purifying yttrium involves purifying element yttrium by high-temperature saturated dissolution, low-temperature recrystallization, high-temperature reduction and vaporization-based removal of impurities, in a simple manner, and at a low cost, such that yttrium element is unlikely to be contaminated by any raw material used in a manufacturing process.
1. A method of purifying yttrium, comprising the steps of:
A: introducing excessive yttrium oxide into nitric acid and heating the yttrium oxide and nitric acid up to a first temperature and stirring, followed by filtering out a minute precipitate to produce saturated yttrium nitrate solution;
B: cooling the saturated yttrium nitrate solution down to a second temperature, keeping the saturated yttrium nitrate solution at the second temperature for a first duration to produce solid precipitate of yttrium nitrate from the saturated yttrium nitrate solution, followed by filtering the saturated yttrium nitrate solution to obtain a first yttrium nitrate solid;
C: heating up the first yttrium nitrate solid in an atmosphere which manifests fluidity and contains hydrogen gas to a third temperature, followed by keeping the first yttrium nitrate solid at the third temperature in the atmosphere for a second duration to reduce yttrium contained in the first yttrium nitrate solid to a metallic state and thus produce liquid yttrium; and
D: changing the temperature of the liquid yttrium to a fourth temperature, followed by keeping the liquid yttrium at the fourth temperature for a third duration to evaporate and effuse an impurity otherwise contained in the liquid yttrium.
2. The method of claim 1 , wherein the first temperature is 60° C.
3. The method of claim 1 , wherein the second temperature is 0° C.
4. The method of claim 1 , wherein the third temperature is 1580° C.
5. The method of claim 1 , wherein the fourth temperature is 1530° C.
6. The method of claim 1 , wherein the first duration is 30 minutes.
7. The method of claim 1 , wherein the second duration is 30 minutes.
8. The method of claim 1 , wherein the third duration is 30 minutes.
9. The method of claim 1 , wherein, in step D, a liquid yttrium at the fourth temperature is placed in a vacuum environment to thereby speed up impurity evaporation and effusion.