Method for producing silicic acid with variable thickening
Process for production of silica having variable thickening wherein a) a product stream I comprising at least a vaporous, hydrolysable and/or oxidizable silicon compound, b) a product stream II comprising oxygen and c) a product stream III comprising at least a combustible gas are made to react, characterized in that d) a feed port in a pipepiece A, said pipepiece A comprising one or more static mixing elements, is used to import product stream I into product stream II, or vice versa and thereby create product stream IV, then e) a feed port in a pipepiece B, said pipepiece B comprising one or more static mixing elements, is used to import product stream III in product stream IV and thereby create product stream V, f) product stream V leaving pipepiece B is imported into a reaction chamber, ignited therein and reacted in a flame, and g) the resultant solid material is separated off.
1. A process for producing silica having variable thickening, the process comprising reacting:
a) a product stream I comprising at least one silicon compound selected from the group consisting of a vaporous silicon compound, a hydrolysable silicon compound, and an oxidizable silicon compound,
b) a product stream II comprising oxygen and
c) a product stream III comprising a combustible gas,
wherein the process comprises:
importing product stream I into product stream II, or importing product stream II into product stream I, through a feed port in a first pipe piece A to create product stream IV, wherein the first pipe piece A comprises at least one static mixing element;
importing product stream III in product stream IV, through a feed port in a second pipe piece B to create product stream V, wherein the second pipe piece B comprises at least one static mixing element;
importing product stream V leaving the second pipe piece B into a reaction chamber, igniting the reaction chamber, and reacting the product stream V in a flame; and
separating solids resulting from the ignition and the reaction,
wherein V B is a velocity with which the product stream III comprising a combustible gas is imported into the product stream IV, V A is a velocity of the product stream IV at a point of importing the product stream III comprising a combustible gas, and
V B /V A ≥4, and
wherein V A is at least 15 Nm/s.
2. The process according to claim 1 , wherein the first and second pipe pieces comprising static mixing elements are designed as a flange mixer.
3. The process according to claim 2 , wherein the flange mixer comprises a single punctiform feed port.
4. The process according to claim 1 , wherein L A /D A is 2-20, where L A is the length of the first pipe piece, D A is the internal diameter of the first pipe piece.
5. The process according to claim 1 , wherein L B /D B is 2-20, where L B is the length of the second pipe piece, D B is the internal diameter of the second pipe piece.
6. The process according to claim 1 , wherein an amount of oxygen is at least sufficient to convert the at least one silicon compound and the combustible gas.
7. The process according to claim 1 , wherein the at least one silicon compound is selected from the group consisting of SiCl 4 , CH 3 SiCl 3 , (CH 3 ) 2 SiCl 2 , (CH 3 ) 3 SiCl, (CH 3 ) 4 Si, HSiCl 3 , (CH 3 ) 2 HSiCl, CH 3 CH 2 CH 2 SiCl 3 , Si(OC 2 H 5 ) 4 , Si(OCH 3 ) 4 and a mixture thereof.
8. The process according to claim 1 , further comprising introducing a stream comprising oxygen and/or steam into the reaction chamber.
9. The process according to claim 1 , further comprising cooling a reaction mixture leaving the reaction chamber to form a cooled reaction mixture and treating the cooled reaction mixture with steam, before separating the solids.