IP Library Granted Patent US 10,253,114
Granted Patent B2
US 10,253,114 · App. 14/891,388 · Granted Apr 9, 2019

Polyolefin modified with nitrogen-containing heterocyclic compound, and adhesive composition containing same

Inventors: Hideyuki Sakata (Hyogo, JP); Kenji Kashihara (Hyogo, JP)
Assignee: TOYOBO CO., LTD.
C08F8/30B32B7/12B32B17/064B32B27/32C08F8/32C08F255/02C08F255/04C09J123/36C09J151/06
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Quick Facts
Patent No.
US 10,253,114
App. No.
14/891,388
Granted
Apr 9, 2019
Kind
B2
Abstract

This invention provides a novel polyolefin modified with a nitrogen-containing heterocyclic compound containing no harmful halogen atoms such as chlorine, and an adhesive composition between a polyolefin substrate and an inorganic substrate such as a glass substrate. A polyolefin modified with a nitrogen-containing heterocyclic compound (C) having a nitrogen-containing heterocyclic compound (B) at the side chain of an acid-modified polyolefin (A).

Claims (23)

1. A polyolefin modified with a nitrogen-containing heterocyclic compound (C) having a nitrogen-containing heterocyclic compound (B) at a side chain of an acid-modified polyolefin (A),

wherein the amount of the nitrogen-containing heterocyclic compound (B) is 3.9 to 7 mass %.

2. The polyolefin modified with a nitrogen-containing heterocyclic compound (C) according to claim 1 , wherein the nitrogen-containing heterocyclic compound (B) is a cyclic alkylene urea derivative.

3. The polyolefin modified with a nitrogen-containing heterocyclic compound (C) according to claim 1 , wherein the nitrogen-containing heterocyclic compound (B) is an imidazolidinone derivative and/or a tetrahydropyrimidinone derivative represented by formula (1) below,

wherein n is an integer of 1 or 2, A is a C 1-20 alkylene group that may have at least one substituent, and R is an amino group, a hydroxy group, a thiol group, an isocyanate group, or an epoxy group.

4. The polyolefin modified with a nitrogen-containing heterocyclic compound (C) according to claim 1 , wherein the nitrogen-containing heterocyclic compound (B) is 1-(2-aminoethyl)-2-imidazolidinone.

5. The polyolefin modified with a nitrogen-containing heterocyclic compound (C) according to claim 1 , wherein the acid-modified polyolefin (A) is a maleic-anhydride-modified polypropylene and/or a maleic-anhydride-modified propylene α-olefin copolymer.

6. A composition of a polyolefin modified with a nitrogen-containing heterocyclic compound containing the polyolefin modified with a nitrogen-containing heterocyclic compound (C) according to claim 1 and an organic solvent (D).

7. The composition according to claim 6 , wherein the organic solvent (D) is contained in an amount of 100 to 1000 parts by mass per 100 parts by mass of the polyolefin modified with a nitrogen-containing heterocyclic compound (C).

8. An adhesive composition comprising the polyolefin modified with a nitrogen-containing heterocyclic compound (C) according to claim 1 .

9. A laminate wherein a polyolefin substrate is adhered to an inorganic substrate by the adhesive composition according to claim 8 .

10. An adhesive composition comprising the composition of a polyolefin modified with a nitrogen-containing heterocyclic compound according to claim 6 .

11. A laminate wherein a polyolefin substrate is adhered to an inorganic substrate by the adhesive composition according to claim 10 .

12. A composition of a polyolefin modified with a nitrogen-containing heterocyclic compound containing:

a polyolefin modified with a nitrogen-containing heterocyclic compound (C) having a nitrogen-containing heterocyclic compound (B) at a side chain of an acid-modified polyolefin (A),

wherein the amount of nitrogen-containing heterocyclic compound (B) is 3.9 to 7 mass %; and

an organic solvent (D), wherein

the organic solvent (D) is a mixture of a solvent (D1) and a solvent (D2),

the solvent (D1) is at least one solvent selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons, alicyclic hydrocarbons, and halogenated hydrocarbons,

the solvent (D2) is at least one solvent selected from the group consisting of alcohol-based solvents, ketone-based solvents, and ester-based solvents, and

the ratio of the solvent (D1)/solvent (D2) is 60 to 98/40 to 2 (mass ratio).

13. An adhesive composition comprising the composition of a polyolefin modified with a nitrogen-containing heterocyclic compound according to claim 12 .

14. A laminate wherein a polyolefin substrate is adhered to an inorganic substrate by the adhesive composition according to claim 13 .

Assignments (3)
CHANGE OF ADDRESS Recorded Aug 7, 2023
From: TOYOBO CO., LTD.
To: TOYOBO CO., LTD.
Reel/Frame 064505/0124 →
DE-MERGER Recorded Aug 7, 2023
From: TOYOBO CO., LTD.
To: TOYOBO MC CORPORATION
Reel/Frame 064505/0803 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2015
From: SAKATA, HIDEYUKI; KASHIHARA, KENJI
To: TOYOBO CO., LTD.
Reel/Frame 037046/0517 →
Priority Claims (2)
JP 2013-105032 · May 17, 2013 · national
JP 2013-105033 · May 17, 2013 · national
Continuity (1)
Related Publication 20160130373A1 · May 12, 2016