LAMINATE
Provided is a laminate including a substrate and a surface layer laminated onto the substrate. The surface layer of the laminate has a microscopic asperity structure formed on the surface thereof on the opposite side from the substrate, this surface layer being a cured material obtained by curing of an active energy beam-curing composition. This active energy beam-curing composition is an active energy beam-curing composition containing particles that, where the interval between adjacent convex portions of the microscopic asperity structure is 100%, have an average particle diameter equal to 80% or more of this interval.
1 . A laminate comprising:
a substrate;
a surface layer laminated on the substrate;
a fine relief structure which has a plurality of convex portions and is formed on a surface of the surface layer on a side opposite to a substrate side, an average interval between the adjacent convex portions is equal to or less than the wavelength of visible light; and
a plurality of particles having an average particle size to be equal to or greater than 80% of an average interval between adjacent convex portions of the fine relief structure, where the average interval is 100%,
wherein
the surface layer and the fine relief structure are cured products of an active energy ray-curable composition, and
a plurality of particles are arranged in the surface layer.
2 . The laminate according to claim 1 , wherein the average particle size is from 100 to 1200% of the average interval between the adjacent convex portions of the fine relief structure, where the average interval is 100%.
3 . The laminate according to claim 1 , wherein the average interval between the adjacent convex portions of the fine relief structure is 25 nm or more and 400 nm or less.
4 . The laminate according to claim 1 , wherein the average particle size is from 80 to 2200 nm and the average interval between the adjacent convex portions is from 100 to 250 nm.
5 . The laminate according to claim 1 , wherein the particles are at least one selected from the group consisting of silica (SiO2), titanium dioxide (TiO2), and a polymer containing at least one selected from the group consisting of methyl methacrylate and styrene.
6 . The laminate according to claim 1 , wherein a shape of the convex portion of the fine relief structure has a structure in which an occupancy rate of a cross-sectional area at the time of cutting a convex portion of the fine relief structure in a direction orthogonal to a height direction of the laminate continuously increases from a tip portion side of the convex portion of the fine relief structure toward a substrate side.
7 . The laminate according to claim 1 , wherein the active energy ray-curable composition contains the particles, and a content of the particles is from 1 to 70 parts by mass with respect to 100 parts by mass of the active energy ray-curable composition.
8 . The laminate according to claim 1 , wherein the active energy ray-curable composition has a content of a trifunctional or higher polyfunctional (meth)acrylate of 10 parts by mass or more and 60 parts by mass or less and a content of a bifunctional (meth)acrylate of 40 parts by mass or more and 90 parts by mass or less where a total amount of polymerizable components of the active energy ray-curable composition is 100 parts by mass.
9 . An antireflective article comprising the laminate according to claim 1 .
10 . A video device comprising the laminate according to claim 1 .
11 . A touch panel comprising the laminate according to claim 1 .