Method for recovering rare earth element
View Patent ↗An object of the present invention is to provide a method according to which a rare earth element can be efficiently recovered from a workpiece containing at least a rare earth element and an iron group element, and also wear and damage to the treatment container can be suppressed, allowing the container to be used repeatedly for a long period of time. The method of the present invention as a means for resolution is characterized in that in the heat treatment of an oxidation-treated workpiece in the presence of carbon, when the oxidation-treated workpiece is placed in a treatment container, a carbon substance is interposed between the oxidation-treated workpiece and the bottom surface of the container, and the heat treatment is performed in an inert gas atmosphere or in vacuum at a temperature of 1300° C. or more.
1. A method for recovering a rare earth element, comprising the steps of:
subjecting a workpiece containing at least a rare earth element and an iron group element to an oxidation treatment to produce an oxidation-treated workpiece,
then placing the oxidation-treated workpiece in a treatment container with a carbon substance interposed between the oxidation-treated workpiece and the bottom surface of the container, and
performing a heat treatment in an inert gas atmosphere or in vacuum at a temperature of 1300° C. or more,
thereby separating a rare earth element in the form of an oxide from an iron group element.
2. The method according to claim 1 , characterized in that at least part of the workpiece is in granular or powder form having a particle size of 500 μm or less.
3. The method according to claim 1 , characterized in that the workpiece has an iron group element content of 30 mass % or more.
4. The method according to claim 1 , characterized in that the workpiece is an R—Fe—B based permanent magnet.
5. The method according to claim 1 , characterized in that the oxidation-treated workpiece housed in a housing member made of paper, wood, synthetic resin, or carbon is placed in the treatment container.
6. The method according to claim 1 , characterized in that a carbon substance housed in a housing member made of paper, wood, synthetic resin, or carbon is interposed between the oxidation-treated workpiece and the bottom surface of the container.
7. The method according to claim 1 , characterized in that a carbon substance is further interposed between the oxidation-treated workpiece and the side surface of the container.
8. The method according to claim 7 , characterized in that the carbon substance interposed between the oxidation-treated workpiece and the side surface of the container is partitioned from the oxidation-treated workpiece by a partition member made of paper, wood, synthetic resin, or carbon.
9. The method according to claim 7 , characterized in that a carbon substance housed in a housing member made of paper, wood, synthetic resin, or carbon is interposed between the oxidation-treated workpiece and the side surface of the container.
10. The method according to claim 1 , characterized in that a carbon substance is further placed in the treatment container.