Method of recovering copper and precious metals
View Patent ↗Provided is a method of recovering copper and one or more precious metals comprising leaching copper-bearing ore and/or concentrate under atmospheric or slightly pressurized conditions at a temperature below the boiling point of the leach solution in a sulfuric acidic solution in the presence of one or more alkali metal or alkali earth metal halides, whereby the total halide concentration is from 30 to 115 g/L, to dissolve copper and to obtain a leaching liquor comprising copper, sulfur species, and halides in solution. The leaching liquor is then subjected to a solid-liquid separation after which a first aqueous pregnant leach solution and a copper depleted leaching residue are obtained. Copper is purified by solvent extraction from the first aqueous pregnant leach solution to obtain a first copper-containing loaded organic solution and a first aqueous raffinate. The copper containing loaded organic solution is stripped and copper is recovered.
1. A method of recovering copper from copper-bearing sulfide ore and/or concentrate comprising the steps of:
(a) leaching copper-bearing ore and/or concentrate under atmospheric or elevated pressure up to 300 kPa at a temperature below the boiling point of the leach solution in a sulfuric acid solution in the presence of one or more alkali metal or alkali earth metal halides, whereby the total halide concentration is from 30 to 115 g/L, to dissolve copper and to obtain a leaching liquor comprising copper, sulfur species, and halides in solution;
(b) solid-liquid separating the leaching liquor to obtain a first aqueous pregnant leach solution and a copper depleted leaching residue;
(c) extracting copper by solvent extraction from the first aqueous pregnant leach solution to obtain a first copper-containing loaded organic solution and a first aqueous raffinate; subjecting a bleed stream of the first aqueous raffinate to a copper hydroxychloride precipitation step; and after solid-liquid separation precipitating impurities from the copper-depleted solution;
(d) stripping copper from the first copper containing loaded organic solution with an electrolyte solution to obtain a copper-depleted organic solution and a copper-containing electrolyte solution; and
(e) recovering copper from the copper containing electrolyte solution.
2. The method as claimed in claim 1 , wherein copper is recovered from the copper-containing electrolyte solution by electrowinning to obtain to obtain metallic copper and a copper-depleted electrolyte solution.
3. The method as claimed in claim 1 , wherein the method comprises recycling a majority of the first aqueous raffinate to the copper leaching step (a).
4. The method as claimed in claim 1 , wherein the method further comprises the steps of:
(f) extracting silver by solvent extraction from the first aqueous raffinate to obtain a silver-containing loaded organic solution and a second aqueous raffinate;
(g) stripping the silver-containing loaded organic solution to obtain a silver-containing aqueous solution; and
(h) recovering silver from the silver-containing aqueous solution.
5. The method as claimed in claim 4 , wherein silver is recovered from silver-containing aqueous solution by precipitation, cementation, or electrowinning.
6. The method as claimed in claim 4 , wherein the method comprises recycling a majority of the second aqueous raffinate to the copper leaching step (a).
7. The method as claimed in claim 4 , wherein silver is extracted from the first aqueous raffinate with an organic solution of a tertiary phosphine sulfide diluted in a hydrocarbon diluent optionally comprising organophosphoric acid, organophosphonic acid, organophosphinic acid, and/or carboxylic acid modifier.
8. The method as claimed in claim 7 , wherein the tertiary phosphine sulfide is triisobutylphosphine sulfide.
9. The method as claimed in claim 7 , wherein the modifier is di-(2-ethylhexyl)phosphoric acid (D2EHPA) or tertiary carboxylic acid.
10. The method as claimed in claim 4 , wherein the silver-containing loaded organic solution is scrubbed with a diluted acid solution to remove impurities, prior to stripping step (g).
11. The method as claimed in claim 4 , wherein the method comprises subjecting a bleed stream of the second aqueous raffinate to a copper hydroxychloride precipitation; and after solid-liquid separation precipitating impurities from the copper-depleted solution.
12. The method as claimed in claim 4 , wherein in the precipitation of copper hydroxychloride from the first aqueous raffinate and/or the second aqueous raffinate the pH is 2.6 to 7.
13. The method as claimed in claim 1 , wherein copper is extracted from the first aqueous pregnant leach solution by solvent extraction utilizing an organic solution comprising hydroxyoxime based copper extractant diluted in a hydrocarbon solvent as the copper extractant.
14. The method as claimed in claim 13 , wherein the hydroxyoxime based copper extractant is selected from aldoximes, ketoximes, and any mixtures thereof.
15. The method as claimed in claim 13 , wherein the volume ratio of the first aqueous pregnant leach solution and the organic solution is between 1:6 and 6:1.
16. The method as claimed in claim 1 , wherein the first copper-containing loaded organic solution is scrubbed with a diluted acid solution to remove impurities, prior to stripping step (d).
17. The method as claimed in claim 1 , wherein leaching of metals in step (a) is conducted in oxidation-reduction potential of 400 to 600 mV Ag/AgCl vs. Pt; and pH from 1.7 to 3.
18. The method as claimed in claim 1 , wherein oxygen, oxygen enriched air, or air is used in leaching of metals in step (a); and it is conducted under total pressure of from 87 to 300 kPa.
19. The method as claimed in claim 1 , wherein the first aqueous pregnant leach solution contains from 1 to 100 g/L copper.