Formation of antireflective surfaces
Technologies are described for methods and systems effective for etching nanostructures in a substrate. The methods may comprise depositing a patterned block copolymer on the substrate. The patterned block copolymer may include first and second polymer block domains. The methods may comprise applying a precursor to the patterned block copolymer to generate an infiltrated block copolymer. The precursor may infiltrate into the first polymer block domain and generate a material in the first polymer block domain. The methods may comprise applying a removal agent to the infiltrated block copolymer to generate a patterned material. The removal agent may be effective to remove the first and second polymer block domains from the substrate. The methods may comprise etching the substrate. The patterned material on the substrate may mask the substrate to pattern the etching. The etching may be performed under conditions to produce nanostructures in the substrate.
1. A method for etching nanostructures in a substrate, the method comprising:
depositing a patterned block copolymer on the substrate, wherein the patterned block copolymer includes a first polymer block domain and a second polymer block domain;
applying a precursor to the patterned block copolymer on the substrate to generate an infiltrated block copolymer on the substrate, wherein the precursor infiltrates into the first polymer block domain and generates a material of metal oxide dots in the first polymer block domain and the precursor does not infiltrate into the second polymer block domain;
applying a removal agent to the infiltrated block copolymer on the substrate to generate a patterned material on the substrate, wherein the removal agent is effective to remove the first polymer block domain and the second polymer block domain from the substrate, and is not effective to remove the material in the first polymer block domain;
plasma etching the substrate, wherein the patterned material on the substrate masks the substrate to pattern the etching;
wherein the etching is performed under etch times sufficiently long enough for metal oxide dots to fall off as tips of etched nanostructures diminish in size and form an antireflective nanotextured surface of etched nanostructures having bases in contact with one another; and
wherein the etched nanostructures are sharp and reduce an average reflectance to about 1% over a wavelength between about 350 to 1000 nm.
2. The method of claim 1 , wherein the etched nanostructures include conical nanotextures having a width tapering gradually from a largest width at a bottom of each nanostructure near the substrate, to a smallest width at a top of a tip of each nanostructure.
3. The method of claim 1 , wherein the etched nanostructures are patterned in an array with a distance between centers of adjacent nanostructures between about 5 nm to about 100 nm.
4. The method of claim 1 , wherein the nanostructures are about 50 nm to about 400 nm high, about 30 to about 60 nm wide at the base and about 5 nm to about 20 nm wide at the tip.
5. The method of claim 1 , wherein the substrate is a polymer, a polyimide, silicon nitride, glass, or silicon.
6. The method of claim 1 , wherein the block copolymer is polystyrene-block-poly(methylmethacrylate) (PS:PMMA).
7. The method of claim 1 , wherein the precursor is a metal organic precursor.
8. The method of claim 7 , wherein the metal organic precursor is tri-methyl aluminum (TMA).
9. The method of claim 1 , wherein the removal agent is oxygen plasma.
10. The method of claim 1 , wherein the substrate is silicon, the plasma etching is with a plasma that is 50-50-10 chlorine, oxygen, hydrogen bromine (HBr) and the plasma etching is performed at room temperature.
11. The method of claim 1 further comprising removing the patterned material with a diluted acid.
12. A method for etching nanostructures in a glass substrate, the method comprising:
depositing a patterned block copolymer on the glass substrate, wherein the patterned block copolymer includes a first polymer block domain and a second polymer block domain;
applying a precursor to the patterned block copolymer on the glass substrate to generate an infiltrated block copolymer on the glass substrate, wherein the precursor infiltrates into the first polymer block domain and generates a material of metal oxide dots in the first polymer block domain and the precursor does not infiltrate into the second polymer block domain;
applying a removal agent of oxygen plasma to the infiltrated block copolymer on the substrate to generate a patterned material on the glass substrate, wherein the removal agent is effective to remove the first polymer block domain and the second polymer block domain from the glass substrate, and is not effective to remove the material in the first polymer block domain;
plasma etching the glass substrate, wherein the patterned material on the glass substrate masks the glass substrate to pattern the etching;
wherein etching is performed under etch times sufficiently long enough for metal oxide dots to fall off as tips of etched nanostructures diminish in size and form an antireflective nanotextured surface of etched nanostructures having bases in contact with one another;
wherein the etched nanostructures are sharp and have a height of about 50 nm to 400 nm, a width of about 30 nm to 60 nm at the bases and a width of about 5 nm to 20 nm at the tips to reduce an average reflectance to about 1% over a wavelength between about 350 to 1000 nm.
13. The method of claim 12 , wherein the etched nanostructures are patterned in an array with a distance between centers of adjacent nanostructures between about 5 nm to about 100 nm.
14. The method of claim 12 , wherein the block copolymer is polystyrene-block-poly(methylmethacrylate) (PS:PMMA).
15. The method of claim 12 , wherein the precursor is a metal organic precursor.
16. The method of claim 15 , wherein the metal organic precursor is tri-methyl aluminum (TMA).
17. The method of claim 12 , further comprising removing the patterned material with a diluted acid.