Organic light-emitting element
View Patent ↗The purpose of the present invention is to provide an organic light-emitting element that comprises an internal light extraction layer on a flexible transparent substrate, that has high luminous efficiency by means of light extraction, and that prevents the breakage and partial or complete separation of electrodes when the organic light-emitting element is repeatedly bent. The organic light-emitting element according to the present invention has an internal light extraction layer, a transparent electrode, and an organic light-emitting layer in this order on the flexible transparent substrate, wherein the value of the ratio (D) represented by formula 1 between the elastic modulus (EM I ) of the surface of the internal light extraction layer and the elastic modulus (EM S ) of the surface of the transparent electrode side of the transparent substrate is within the range of 100±30%. D (%)=(EM I /EM S )×100(%). Formula 1
1. An organic light-emitting element comprising a flexible transparent substrate having thereon an internal light extracting layer, a transparent electrode, and an organic light-emitting layer in that order,
wherein the flexible transparent substrate contains a film substrate and at least one gas barrier layer in that order, and
wherein a ratio D of an elastic modulus (EM I ) of a surface of the internal light extracting layer to an elastic modulus (EM s ) of a surface of the transparent electrode side of the flexible transparent substrate is in the range of 100±30%,
the ratio D being defined by Scheme 1,
D (%)=(EM I /EM s )×100(%). Scheme 1:
2. The organic light-emitting element of claim 1 ,
wherein the internal light extracting layer has:
a refractive index in the range of 1.7 to 2.5 when measured at a wavelength of 550 nm;
an average transmittance of 50% or more in the wavelength range of 450 nm to 700 nm; and
a haze value of 30% or more.
3. The organic light-emitting element of claim 1 , wherein the at least one gas barrier layer contains an inorganic precursor compound.
4. An organic light-emitting element comprising a flexible transparent substrate having thereon an internal light extracting layer, a transparent electrode, and an organic light-emitting layer in that order,
wherein the flexible transparent substrate contains a film substrate and at least one gas barrier layer in that order, and the internal light extracting layer contains a light scattering layer and a smoothing layer, and
wherein a ratio D of an elastic modulus (EM I ) of a surface of the internal light extracting layer to an elastic modulus (EM s ) of a surface of the transparent electrode side of the flexible transparent substrate is in the range of 100±30%,
the ratio D being defined by Scheme 1,
D (%)=(EM I /EM s )×100(%). Scheme 1:
5. The organic light-emitting element of claim 4 ,
wherein the light scattering layer contains light scattering particles;
an average particle size of the light scattering particles is in the range of 0.2 to 1 μm; and
the light scattering layer has a refractive index in the range of 1.7 to 3.0 when measured at a wavelength of 550 nm.
6. The organic light-emitting element of claim 4 ,
wherein the internal light extracting layer has:
a refractive index in the range of 1.7 to 2.5 when measured at a wavelength of 550 nm;
an average transmittance of 50% or more in the wavelength range of 450 nm to 700 nm; and
a haze value of 30% or more.
7. The organic light-emitting element of claim 4 , wherein the at least one gas barrier layer contains an inorganic precursor compound.
8. The organic light-emitting element of claim 7 , wherein the inorganic precursor compound is at least one of polysiloxane, polysilazane, or polysiloxazane.
9. The organic light-emitting element of claim 4 , wherein the smoothing layer includes a high-refractive index layer with a refractive index of 1.7 to 2.5 measured at a wavelength of 550 nm.
10. The organic light-emitting element of claim 9 , wherein the smoothing layer has an average surface roughness Ra of less than 100 nm.
11. The organic light-emitting element of claim 9 , wherein the inorganic precursor compound is at least one of polysiloxane, polysilazane, or polysiloxazane.