Self-writing waveguide with nanoparticles
View Patent ↗Technologies are generally described for fabricating a self-writing waveguide. Two photo-reactive liquid monomers, each infused with a photo-initiator, may be mixed and dissolved in a carrier solvent to form a mixture. Nanoparticles may be added to the mixture to form a gel. A focused light beam may be provided to cure one of the monomers, initiating polymerization to form a core of the self-writing waveguide. An optional exposure to an optical source, a heat source, or an electron beam source may cure the other monomer, initiating polymerization to form a cladding of the self-writing waveguide. The self-writing waveguide may be formed in a substantially tubular structure or a planar film structure.
1. A method for fabricating a self-writing waveguide, the method comprising:
mixing a first photo-reactive liquid monomer and a second photo-reactive liquid monomer to form a mixture, wherein the first photo-reactive liquid monomer is infused with a photo-initiator;
adding nanoparticles to the mixture to form a gel, wherein
the nanoparticles comprise one or more of: fumed silica and acidic silica, and
a type and a number of the nanoparticles added is based on a curing speed of the mixture and a mechanical modulus of the mixture;
selecting a stiffness of the self-writing waveguide by adjusting a fraction of the nanoparticles in the mixture;
providing a focused light beam to cure the first photo-reactive liquid monomer;
exposing the mixture to at least one of an optical source, a heat source, and an electron beam source for curing the second photo-reactive liquid monomer upon curing the first photo-reactive liquid monomer; and
bleaching the photo-initiator by exposing the mixture to one of the optical source, the heat source, and the electron beam source.
2. The method of claim 1 , further comprising terminating the focused light beam when the first photo-reactive liquid monomer is substantially cured.
3. The method of claim 1 , wherein the gel allows a free diffusion of the liquid form of the first photo-reactive and second photo-reactive monomers.
4. The method of claim 1 , further comprising selecting the first photo-reactive liquid monomer, the second photo-reactive liquid monomer, and the nanoparticles further based on a refractive index difference between the first and second photo-reactive liquid monomers upon curing.
5. The method of claim 1 , wherein the first photo-reactive liquid monomer is a cationic monomer.
6. The method of claim 1 , wherein the first photo-reactive liquid monomer is infused with a cationic photo-initiator.
7. The method of claim 1 , further comprising selecting the first photo-reactive liquid monomer, the second photo-reactive liquid monomer, and the nanoparticles such that the self-writing waveguide has an operational temperature range of about −55° C. to about 125° C.
8. The method of claim 1 , further comprising providing the focused tight beam as a laser beam.
9. The method of claim 8 , wherein the laser beam has a wavelength of about 390 nm to about 980 nm.
10. The method of claim 1 , further comprising terming the self-writing waveguide in a substantially tubular structure or a planar film structure, wherein the cured first photo-reactive liquid monomer forms a core and the cured second photo-reactive liquid monomer forms a cladding of the self-writing waveguide.
11. The method of claim 10 , further comprising forming the self-writing waveguide in the planar film structure in situ, as a laminate on a circuit board backplane.
12. The method of claim 10 , further comprising forming the self-writing waveguide in the planar film for lamination using a roll-to-roll process.
13. The method of claim 10 , wherein the self-writing waveguide in the planar film is free-standing and self-supporting.
14. The method of claim 1 , wherein mixing the first photo-reactive liquid monomer and the second photo-reactive liquid monomer comprises dissolving the first photo-reactive and second photo-reactive liquid monomers in a carrier solvent prior to adding the nanoparticles.
15. The method of claim 1 , wherein the first photo-reactive liquid monomer comprises a polymerizable cationic monomer or a polymerizable ionic monomer.
16. The method of claim 1 , wherein the second photo-reactive liquid monomer comprises a polymerizable radical monomer.
17. The method of claim 1 , further comprising adding the nanoparticles to the mixture by shear-mixing or sonication.
18. The method of claim 1 , wherein mixing comprises mixing a cationic monomer infused with a cationic photo-initiator at a first wavelength and a radical monomer infused with a near infrared radiation (NIR) free radical initiator to form the mixture, dissolving the mixture in a carrier solvent, and adding silica-based nanoparticles.
19. A method for fabricating a self-writing waveguide, the method comprising:
mixing a first photo-reactive liquid monomer and a second photo-reactive liquid monomer to form a mixture;
adding nanoparticles to the mixture to form a gel, wherein
the nanoparticles comprise one or more of: fumed silica and acidic silica, and
a type and a number of the nanoparticles added is based on a curing speed of the mixture and a mechanical modulus of the mixture;
selecting a stiffness of the self-writing waveguide by adjusting a fraction of the nanoparticles in the mixture;
providing a focused light beam to cure the first photo-reactive liquid monomer; and
terminating the focused light beam when the first photo-reactive liquid monomer is substantially cured.
20. The method of claim 19 , wherein the second photo-reactive liquid monomer remains in a liquid form while the first photo-reactive liquid monomer is cured.
21. The method of claim 19 , wherein preparing the mixture of the first photo-reactive liquid monomer and the second photo-reactive liquid monomer comprises infusing the first photo-reactive liquid monomer and the second photo-reactive liquid monomer with respective photo-initiators.