Secondary battery and method for manufacturing same
View Patent ↗An object of the present invention is to provide a high-quality secondary battery having high electric characteristics and high reliability, the secondary battery preventing a shortcut between a positive electrode and a negative electrode by means of an insulating material and preventing or reducing an increase in volume and deformation of a battery electrode assembly, and a method for manufacturing the same. Secondary battery 100 according to the present invention includes a battery electrode assembly including positive electrode 1 and negative electrode 6 alternately stacked via separator 20 . Positive electrode 1 and negative electrode 2 each includes current collector 3 or 8 and active material 2 or 7 applied to current collector 3 or 8 . Active material 2 A positioned on one surface of positive electrode 1 of current collector 3 includes flat part 2 A 1 and small-thickness part (thin-layer part) 2 A 3 positioned on the end portion side relative to flat part 2 A 1 , the small-thickness part 2 A 3 having a thickness that is smaller than that of flat part 2 A 1 . A part of active material 2 B positioned on another surface of current collector 3 of positive electrode 1 , the part facing thin-layer part 2 A 3 of active material 2 A positioned on the one surface via current collector 3 is a flat part having a constant thickness.
1. A secondary battery comprising a battery electrode assembly including a positive electrode and a negative electrode alternately stacked via a separator, wherein:
the positive electrode and the negative electrode each includes a current collector and an active material applied to the current collector;
the active material which is positioned on one surface of the current collector of the positive electrode, consists essentially of a large-thickness portion and a small-thickness portion, and the small-thickness portion is positioned on an end portion side relative to the large-thickness portion, and the small-thickness portion has a thickness that is smaller than that of the large-thickness portion;
the active material which is positioned on the other surface of the current collector of the positive electrode, has an end portion, and the end portion of the active material which is positioned on the other surface of the current collector, faces the small-thickness portion of the active material positioned on the one surface of the current collector, across the current collector, and consists essentially of a flat portion;
the active material which is positioned on the one surface of the current collector of the positive electrode and the active material which is positioned on the other surface of the current collector of the positive electrode are asymmetric to each other around the current collector,
the small-thickness portion of the active material positioned on the one surface of the current collector of the positive electrode includes at least one from among a thin-layer portion, an inclined portion whose thickness continuously decrease, and a stepped portion whose thickness intermittently decrease.
2. The secondary battery according to claim 1 , wherein an insulating material is positioned so that: the insulating material covers a boundary part between a coated portion to which the active material has been applied and an uncoated portion to which the active material has not been applied in the positive electrode; and one end portion of the insulating material is positioned on the small-thickness portion of the active material positioned on the one surface of the current collector of the positive electrode.
3. The secondary battery according to claim 2 , wherein a difference in thickness between the large-thickness portion and the small-thickness portion of the active material positioned on the one surface of the current collector of the positive electrode is equal to or larger than a thickness of the insulating material.
4. The secondary battery according to claim 3 , wherein the insulating material is provided on each of the opposite surfaces of the current collector of the positive electrode, and the difference in thickness between the large-thickness portion and the small-thickness portion of the active material positioned on the one surface of the current collector of the positive electrode is no less than twice the thickness of the insulating material.
5. The secondary battery according to claim 2 , wherein a total sum of the thickness of the insulating material, a thickness of a part of the active material on the one surface of the current collector of the positive electrode on which the insulating material is disposed, and a thickness of a part of the active material of the negative electrode, which faces the insulating material across the separator, is equal to or smaller than a total sum of the thickness of the large-thickness portion of the active material of the positive electrode and a thickness of a part of the active material of the negative electrode, which faces the large-thickness portion of the active material of the positive electrode across the separator.
6. The secondary battery according to claim 1 , wherein the active material positioned on the other surface of the current collector of the positive electrode consists essentially of only the flat portion.
7. The secondary battery according to claim 1 , wherein:
the active material which is positioned on one surface of the current collector of the negative electrode, consists essentially of a large-thickness portion and a small-thickness portion having a thickness that is smaller than that of the large-thickness portion; and
the active material which is positioned on the other surface of the current collector of the negative electrode, has an end portion, and the end portion of the active material which is positioned on the other surface of the current collector, faces the small-thickness portion of the active material positioned on the one surface, across the current collector, and consists essentially of a flat portion.
8. The secondary battery according to claim 7 , wherein the small-thickness portion of the active material positioned on the one surface of the current collector of the negative electrode faces an insulating material positioned on the active material of the positive electrode, across the separator.