Process for the purification of polycarbonate

1. A process of purifying a polycarbonate from an interfacial polymerization product mixture comprising an aqueous phase and an organic phase comprising a first organic solvent, the polycarbonate, a catalyst, and ions, the process comprising:

separating the aqueous phase and the organic phase to form a separated aqueous feed stream and a separated organic stream;

extracting the catalyst and the ions from the separated organic stream to form a purified polycarbonate stream and an extracted aqueous feed stream, wherein at least one of the separated aqueous feed stream and the extracted aqueous feed stream comprise an organic portion and an aqueous portion;

purifying an aqueous stream comprising one or both of the separated aqueous feed stream and the extracted aqueous feed stream by

adjusting a viscosity of the organic portion to be less than or equal to 40 centipoise by adding a second organic solvent to the aqueous stream to form a combined stream;

optionally, adjusting a ratio of the aqueous portion to the organic portion to 1.0 to 20.0 by adding an aqueous solution to the aqueous stream; and

separating the combined stream to form a purified aqueous stream, wherein less than or equal to 3 vol % of the purified aqueous stream is the organic portion.

2. The process of claim 1 , wherein the organic portion of the aqueous stream has a viscosity of less than or equal to 30 centipoise.

3. The process of claim 2 , wherein the organic portion of the aqueous stream has a viscosity of 20 to 30 centipoise.

4. The process of claim 1 , comprising adjusting the ratio of the aqueous portion to the organic portion to 1.0 to 15.0 by adding the aqueous solution.

5. The process of claim 4 , wherein the ratio of the aqueous portion to the organic portion is 1.0 to 10.0.

6. The process of claim 4 , wherein the ratio of the aqueous portion to the organic portion is 1.0 to 6.0.

7. The process of claim 1 , further comprising adjusting a pH of the aqueous portion 1.0 to 10.0 by adding an aqueous solvent.

8. The process of claim 7 , wherein the pH is 1.0 to 6.0.

9. The process of claim 1 , wherein less than or equal to 2 vol % of the purified aqueous stream is the organic portion.

10. The process of claim 9 , wherein less than or equal to 1 vol % of the purified aqueous stream is the organic portion.

11. The process of claim 1 , wherein one or both of the first organic solvent and the second organic solvent comprises methylene chloride, ethylene chloride, or a combination comprising one or both of the foregoing.

12. The process of claim 1 , wherein the extracting the catalyst occurs prior to or during the extracting of the ions.

13. The process of claim 1 , wherein the separating aqueous phase and the organic phase and the separating the combined stream occurs via a high shear rate centrifuge.

14. The process of claim 1 , wherein the extracting of one or both of the catalyst and the ion occurs via one or more extraction columns.

15. The process of claim 1 , wherein the polycarbonate comprises a bisphenol A homopolymer, a copolycarbonate comprising bisphenol A carbonate units and bulky bisphenol carbonate units derived from a bisphenol having at least 12 carbon atoms, or a polyestercarbonate comprising bisphenol A carbonate units and terephthalate-isophthalate acid-bisphenol A ester units.

16. The process of claim 15 , wherein the polycarbonate comprises a copolymer comprising bisphenol A carbonate units and 2-phenyl-3,3′-bis(4-hydroxyphenyl) phthalimidine carbonate units, a copolymer comprising bisphenol A carbonate units and 1,1-bis(4-hydroxy-3-methylphenyl)cyclohexane carbonate units, or a copolymer comprising bisphenol A carbonate units and isophorone bisphenol carbonate units.

17. The process of claim 1 , further comprising further purifying the purified polycarbonate stream.

18. The process of claim 1 , comprising the adjusting the ratio of the aqueous portion to the organic portion to 1.0 to 20.0 by adding the aqueous solution to the aqueous stream.