Optical glass and use thereof
An optical glass that is oxide glass, containing Si 4+ , B 3+ , La 3+ , Ti 4+ , Nb 5+ , and Zr 4+ ; containing, denoted as cation %, Si 4+ and B 3+ of 5 to 55% in total, La 3+ of 10 to 50%, with a total content of La 3+ , Gd 3+ , Y 3+ and Yb 3+ ≦70%, and Ti 4+ , Nb 5+ , Ta 5+ and W 6+ of 22 to 55% in total, with a content of Ti 4+ ≦22%, wherein [Si 4+ /(Si 4+ +B 3+ )]≦0.40; the total content of La 3+ , Gd 3+ , Y 3+ , Yb 3+ , Zr 4+ , Ti 4+ , Nb 5+ , Ta 5+ , W 6+ and Bi 3+ ≧65%; [Y 3+ /(La 3+ +Gd 3+ +Y 3+ +Yb 3+ )]≦0.12; [Ba 2+ /(La 3+ +Gd 3+ +Y 3+ +Yb 3+ )]≦0.40; [(Zr 4+ +Ti 4+ +Nb 5+ +Ta 5+ +W 6+ )/Zr 4+ ]≧2; (Ti 4+ /B 3+ )≧0.85; and an Abbé number νd is in a range from 23 to 35, and a refractive index nd satisfies nd≧2.205−(0.0062×νd).
1. Optical glass, which is oxide glass:
comprising Si 4+ , B 3+ , La 3+ , Ti 4+ , Nb 5+ , and Zr 4+ as essential components;
comprising, denoted as cation %;
Si 4+ and B 3+ of 5 to 35% in total,
La 3+ of 10 to 50%, with a total content of La 3+ , Gd 3+ , Y 3+ and Yb 3+ being from 11% to 70%, and
Ti 4+ , Nb 5+ , Ta 5+ and W 6+ of 22 to 55% in total, with a content of Ti 4+ being from 10% to 22%, wherein
a cation ratio of a content of Si 4+ to a total content of Si 4+ and B 3+, Si 4+ /(Si 4+ +B 3+ ), is from 0.10 to 0.40;
a total content of La 3+ , Gd 3+ , Y 3+ , Zr 4+ , Ti 4+ , Nb 4+ , Ta 5+ , W 6+ and Bi 3 + is equal to or more than 65%;
a cation ratio of a content of Y 3+ to a total content of La 3+ , Gd 3+ , Y 3+ and Yb 3 + , Y 3+ /(La 3+ +Gd 3+ +Y 3+ +Yb 3+ ), is equal to or less than 0.12;
a cation ratio of a content of Ba 2+ to a total content of La 3+ , Gd 3+ , Y 3+ and Yb 3+ , Ba 2+ /(La 3+ +Gd 3+ +Y 3+ +Yb 3+ ), is equal to or less than 0.40;
a cation ratio of a total content of Zr 4+ , Ti 4+ , Nb 5+ , Ta 5+ and W 6+ to a content of Zr 4+ , (Zr 4+ Ti 4+ +Ta 5+W 6+ )/Zr 4+ , is equal to or more than 2;
a cation ratio of a content of Ti 4+ to a content of B 3+ , Ti 4+ /B 3+ , is equal to or more than 0. 85; and
an Abbé number νd is in a range from 23 to 35, and a refractive index nd satisfies Expression (1) below,
nd≧ 2.205−(0.0062 ×νd ) (1).
2. The optical glass according to claim 1 , wherein a cation ratio of a total content of Nb 5+ and Ta 5+ to a total content of Ti 4 + , Nb 5+ , Ta 5+ and W 6+ , (Nb 5+ +Ta 5+ )/(Ti 4+ +Nb 5+ Ta 5+ +W 6+ ), is from 0.10 to 0.41.
3. The optical glass according to claim 1 , which comprises Zr 4+ in an amount equal to or more than 1 cation %.
4. A press-molding glass gob, which is comprised of the optical glass according to claim 1 .
5. An optical element blank, which is comprised of the optical glass according claim 1 .
6. An optical element, which is comprised of the optical glass according to claim 1 .