Shear spun sub-micrometer fibers
View Patent ↗A process including shearing a first dispersion medium and a second dispersion medium under conditions that precipitate a plurality of polymeric fibers; and collecting the plurality of polymeric fibers at a rate of at least 300 grams/hour. The first dispersion medium is a solution including at least one polymeric component. The at least one polymeric component includes a polyetherimide component selected from the group consisting of polyetherimide homopolymers, polyetherimide co-polymers, polyetherether ketones homopolymers, polyetherether ketones copolymers, polyphenylene sulfones homopolymers, polyphenylene sulfones copolymers, and combinations thereof. Products produced by the process can be non-woven paper, medical implants, ultra-fine filters, membranes, hospital gowns, electrical insulation paper, honeycomb structures and personal hygiene products, dialyzers, blood, oxygenator filters, intravenous (IV) filters, diagnostic test filters, and blood/apheresis filters.
1. A process comprising:
shearing a first dispersion medium and a second dispersion medium under conditions that precipitate a plurality of staple polymeric fibers,
wherein each of the plurality of staple polymeric fibers has a length to diameter ratio of greater than 100:1,
wherein each of the plurality of staple polymeric fibers has a diameter ranging from 0.05 to 5 micrometers,
wherein each of the plurality of staple polymeric fibers is insoluble in the second dispersion medium,
wherein the first dispersion medium is a solution comprising at least one of (a) polyetherimide homopolymers and polyetherimide co-polymers;
wherein the second dispersion medium comprises water, ethyl alcohol, propyl glycol, propylene glycol, glycerol, or combinations thereof and further comprises meta-cresol, veratrol, ortho-dichlorobenzene, N-methyl pyrrolidone, chloroform, tetrahydrofuran, dimethylformamide, dimethylacetamide, or combinations thereof,
wherein the first dispersion medium is insoluble in the second dispersion medium; and
collecting the plurality of polymeric staple fibers at a rate of at least 300 grams/hour.
2. The process of claim 1 , wherein the first dispersion medium is injected into the second dispersion medium.
3. The process of claim 1 , wherein the first dispersion medium further comprises meta-cresol, veratrol, ortho-dichlorobenzene, N-methyl pyrrolidone, chloroform, tetrahydrofuran, dimethylformamide, dimethylacetamide, or combinations thereof.
4. The process of claim 1 , further comprising producing a non-woven web from the collected fibers by depositing the plurality of polymeric staple fibers onto a carrier substrate, a functional sheet, a film, a non-woven, a rolled good product, or combinations thereof.
5. The process of claim 4 , further comprising at least partially removing the solvent from the fibers before the fibers are deposited.
6. The process of claim 4 , wherein the non-woven web has a width of at least 150 mm.
7. The process of claim 1 , further comprising producing a non-woven web from the collected fibers, wherein the non-woven web is formed by entangling the fibers.
8. The process of claim 7 , further comprising consolidating the non-woven web under pressure.
9. The process of claims 1 , wherein the process is carried out at −30 to 210° C.
10. The process of claims 1 , wherein the first dispersion medium has a viscosity of from 10 to 20,000 cP, and the second dispersion medium has a viscosity of from 10 to 20,000 cP.
11. The process of claim 1 , wherein each of the plurality of polymeric fibers is provided with at least one additional functionality imparting at least one of therapeutic activity, catalytic activity microelectronic activity, micro-optoelectronic activity, magnetic activity, biological activity, or combinations thereof.
12. The process of claim 4 , wherein the non-woven web contains less than 10 wt % of polyvinyl pyrrolidine, polymethyl methacrylate, polyvinylidene fluoride, polypropylene, polycarbonate, polyethylene oxide, agarose, polyvinylidene fluoride, polylactic glycolic acid, nylon 6, polycaprolactone, polylactic acid, polybutylene terephthalate, or combinations thereof.
13. The process of claim 1 , wherein the polyetherimide component is a reaction product of at least one from the group consisting of (i) 4,4′-bisphenol A dianhydride and diamine monomers; (ii) 4,4′-bisphenol A dianhydride and meta-phenylene diamine monomers and (iii) 4,4′-bisphenol A dianhydride and paraphenylene diamine monomers; wherein the reaction product is endcapped with at least one of (a) aniline and (b) phthalic anhydride.
14. The process of claim 1 , wherein the polyetherimide component is a thermoplastic resin composition comprising:
the polyetherimide, and
a phosphorous-containing stabilizer, in an amount that is effective to increase the melt stability of the polyetherimide, wherein the phosphorous-containing stabilizer exhibits a low volatility such that, as measured by thermogravimetric analysis of an initial amount of a sample of the phosphorous-containing stabilizer, greater than or equal to 10 percent by weight of the initial amount of the sample remains unevaporated upon heating of the sample from room temperature to 300° C. at a heating rate of 20° C. per minute under an inert atmosphere.