Polarizing plate, method for manufacturing same and liquid-crystal display device comprising same
The present invention relates to a polarizing plate including a polarizer and a polyester film formed on an upper side of the polarizer, wherein the polyester film has a maximum thermal shrink angle of about 10° or less, and any one of a refractive index of x-axis direction nx at a wavelength of 550 nm and a refractive index of y-axis direction ny at a wavelength of 550 nm of about 1.65 or more; a method of preparing the polarizing plate; and a liquid crystal display apparatus comprising the polarizing plate.
1. A polarizing plate comprising:
a polarizer; and
a polyester film formed on an upper side of the polarizer,
wherein the polyester film has a maximum thermal shrink angle of about 10° or less, a refractive index of an x-axis direction (nx) at a wavelength of 550 nm of about 1.65 or more, a refractive index of a y-axis direction (ny) at a wavelength of 550 nm of about 1.65 or less, and a front retardation (Ro) of about 5,000 to about 15,000 nm at a wavelength of 550 nm,
wherein the polyester film has a retardation in a thickness direction (Rth) of 10,000 nm to 13,000 nm at a wavelength of 550 nm, as calculated by Equation 2:
Rth ={( nx+ny )/2 −nz}×d Equation 2
wherein, in Equation 2, nx, ny and nz are refractive indices in an x-axis direction, a y-axis direction and a z-axis direction of the polyester film at a wavelength of 550 nm, respectively, and d is a thickness of the film in nm.
2. The polarizing plate according to claim 1 , wherein an absolute value of nx−ny is about 0.1 to about 0.2.
3. The polarizing plate according to claim 1 , wherein the polyester film has a maximum thermal shrinkage of about 0.8% or less.
4. The polarizing plate according to claim 1 , wherein the polyester film has an absolute value of a molecular orientation angle (θr) of a polyester molecule based on a transverse direction (TD) of about 0° to about 5°.
5. The polarizing plate according to claim 1 , wherein the polyester film has a thickness of about 25 to about 115 μm.
6. The polarizing plate according to claim 1 , wherein the front retardation (Ro) of the polyester film is about 10,100 to about 12,000 nm.
7. The polarizing plate according to claim 1 , wherein the polyester film is a TD drawn film.
8. The polarizing plate according to claim 1 , wherein the polyester film has a degree of biaxiality (NZ) of about 1.8 or less at a wavelength of 550 nm, as represented by Equation 1:
NZ =( nx−nz )/( nx−ny ) Equation 1
(wherein nx, ny and nz are refractive indices in an x-axis direction, a y-axis direction and a z-axis direction of the polyester film at a wavelength of 550 nm, respectively).
9. The polarizing plate according to claim 1 , wherein the polyester film is a film formed of at least one of polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate and polybutylene naphthalate.
10. The polarizing plate according to claim 1 , further comprising an optical film on a lower side of the polarizer.
11. The polarizing plate according to claim 10 , wherein the optical film has a front retardation (Ro) of about 40 to about 60 nm at a wavelength of 550 nm.
12. The polarizing plate according to claim 10 , wherein the optical film is a film formed of at least one of cellulose, polyester, cyclic polyolefin, polycarbonate, polyether sulfone, polysulfone, polyimide, polyimide, polyolefin, polyacrylate, polyvinyl alcohol, polyvinyl chloride, and polyvinylidene chloride resins.
13. The polarizing plate according to claim 1 , wherein the polarizing plate has a polarization degree of about 99.99% or more, and a transmittance of about 40% or more.
14. A liquid crystal display apparatus comprising the polarizing plate according to claim 1 .
15. A polarizing plate comprising:
a polarizer; and
a polyester film formed on an upper side of the polarizer,
wherein the polyester film has an absolute value of a molecular orientation angle (θr) of about 5° or less, and
wherein the polyester film has a refractive index of an x-axis direction (nx) at a wavelength of 550 nm of about 1.65 or more, a refractive index of a y-axis direction (ny) at a wavelength of 550 nm of about 1.65 or less, and a front retardation (Ro) of about 5,000 to about 15,000 nm at a wavelength of 550 nm,
wherein the polyester film has a retardation in a thickness direction (Rth) of 10,000 nm to 13,000 nm at a wavelength of 550 nm, as calculated by Equation 2:
Rth ={( nx+ny )/2 −nz}×d Equation 2
wherein, in Equation 2, nx, ny and nz are refractive indices in an x-axis direction, a y-axis direction and a z-axis direction of the polyester film at a wavelength of 550 nm, respectively, and d is a thickness of the film in nm.