Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
View Patent ↗Provided is a system for treating a flowing exhaust gas comprising a lean NOx trap, a catalyzed soot filter, an ammonia or an ammonia precursor metering system for metering ammonia or an ammonia precursor into the flowing exhaust gas; and an SCR catalyst, wherein the SCR catalyst is disposed downstream of the lean NOx trap and comprises copper and/or iron supported on a small pore molecular sieve.
1. A system for treating a flowing exhaust gas comprising:
(a) a lean NOx trap;
(b) a catalyzed soot filter;
(c) an ammonia or an ammonia precursor metering system for metering ammonia or an ammonia precursor into the flowing exhaust gas; and
(d) an SCR catalyst, wherein the SCR catalyst is disposed downstream of the lean NOx trap and comprises copper and/or iron supported on a small pore molecular sieve, wherein the small pore molecular sieve has a framework selected from the group consisting of AEI, AFT, AFX, DDR, ERI, LEV, KFI, and SAV.
2. The system of claim 1 , wherein said metering is controlled in response to the quantity of nitrogen oxides in the exhaust gas.
3. The system of claim 1 , wherein the small pore molecular sieve is a SAPO.
4. The system of claim 1 , wherein the small pore molecular sieve has a silica-to-alumina ratio of 8 to 150.
5. The system of claim 1 , wherein the small pore molecular sieve has an AEI framework.
6. The system of claim 1 , wherein the catalyzed soot filter comprises a copper-loaded small pore molecular sieve.
7. The system of claim 1 , wherein the SCR catalyst is coated on flow-through monolith.
8. The system of claim 1 , wherein the catalyzed soot filter is coated with an SCR catalyst.
9. The system of claim 1 , wherein the small pore molecular sieve has an AFT Framework.
10. The system of claim 1 , wherein the small pore molecular sieve has an AFX Framework.
11. The system of claim 1 , wherein the small pore molecular sieve has an DDR framework.
12. The system of claim 1 , wherein the small pore molecular sieve has an ERI framework.
13. The system of claim 1 , wherein the small pore molecular sieve has an LEV framework.
14. The system of claim 1 , wherein the small pore molecular sieve has an KFI framework.
15. The system of claim 1 , wherein the small pore molecular sieve has an SAV framework.