Nitride semiconductor
View Patent ↗To provide a high-quality nitride semiconductor ensuring high emission efficiency of a light-emitting element fabricated. In the present invention, when obtaining a nitride semiconductor by sequentially stacking a one conductivity type nitride semiconductor part, a quantum well active layer structure part, and a another conductivity type nitride semiconductor part opposite the one conductivity type, the crystal is grown on a base having a nonpolar principal nitride surface, the one conductivity type nitride semiconductor part is formed by sequentially stacking a first nitride semiconductor layer and a second nitride semiconductor layer, and the second nitride semiconductor layer has a thickness of 400 nm to 20 μm and has a nonpolar outermost surface. By virtue of selecting the above-described base for crystal growth, an electron and a hole, which are contributing to light emission, can be prevented from spatial separation based on the QCSE effect and efficient radiation is realized. Also, by setting the thickness of the second nitride semiconductor layer to an appropriate range, the nitride semiconductor surface can avoid having extremely severe unevenness.
1. A nitride semiconductor comprising:
a nitride semiconductor part having a first conductivity;
a quantum well active layer structure part; and
a nitride semiconductor part having a second conductivity, said second conductivity being a conductivity opposite of said first conductivity, which are stacked in this order on a nitride principal surface of a base,
wherein the principal nitride surface of the base is a nonpolar nitride surface,
wherein said nitride semiconductor part having a first conductivity comprises a first nitride semiconductor layer and a second nitride semiconductor layer, which are stacked in this order,
wherein said second nitride semiconductor layer has a thickness of 400 nm to 20 μm and has a nonpolar outermost surface,
wherein a photoluminescence lifetime (τ(PL)) of said quantum well active layer structure part, as determined by time-resolved PL measurement at room temperature under low excitation density condition, is 1.0 ns or more, and
wherein said base is a GaN self-supporting substrate.
2. The nitride semiconductor as claimed in claim 1 , wherein the photoluminescence lifetime (τ(PL)) is 1.5 ns or more.
3. The nitride semiconductor as claimed in claim 1 , wherein the internal quantum efficiency of said quantum well active layer structure part, as determined by CW-PL measurement under low excitation density condition, is 20% or more.
4. The nitride semiconductor as claimed in claim 1 , wherein the internal quantum efficiency of said quantum well active layer structure part, as determined by pulsed PL measurement under low excitation density condition, is 20% or more.
5. The nitride semiconductor as claimed in claim 1 , wherein said first conductivity is n-type conductivity and said second conductivity is p-type conductivity.
6. The nitride semiconductor as claimed in claim 1 , wherein the nitride principal surface of said base is a crystal plane with ±10° or less from the (1-100) plane (m-plane).
7. The nitride semiconductor as claimed in claim 1 , wherein the silicon (Si) concentration in said first nitride semiconductor layer is 1×10 21 cm −3 or less.
8. The nitride semiconductor as claimed in claim 1 , wherein the silicon concentration in said second nitride semiconductor layer is from 1×10 17 to 6×10 19 cm −3 .
9. The nitride semiconductor as claimed in claim 1 , wherein the thickness L 1 of said first nitride semiconductor layer is from 0.1 to 300 nm.
10. The nitride semiconductor as claimed in claim 1 , wherein a first internal quantum efficiency of said quantum well active layer structure part, as determined by CW-PL measurement under low excitation density condition, is 30% or more.
11. The nitride semiconductor as claimed in claim 1 , wherein a first internal quantum efficiency of said quantum well active layer structure part, as determined by CW-PL measurement under low excitation density condition, is 35% or more.
12. The nitride semiconductor as claimed in claim 1 , wherein a second internal quantum efficiency of said quantum well active layer structure part, as determined by pulsed PL measurement under low excitation density condition, is 20% or more.
13. The nitride semiconductor as claimed in claim 1 , wherein a second internal quantum efficiency of said quantum well active layer structure part, as determined by pulsed PL measurement under low excitation density condition, is 25% or more.
14. The nitride semiconductor as claimed in claim 1 , wherein the photoluminescence lifetime (τ(PL)) is more than 1.8 ns.