Batteries and electrolytes incorporating fluoroethylene carbonate
View Patent ↗This disclosure relates to a battery and a method for its manufacture. An example method includes forming an anode comprising silicon monoxide and a forming a cathode comprising lithium cobalt oxide. The method also includes arranging the anode, the cathode, and a separator in a layered arrangement. The method further includes winding the layered arrangement to form a wound arrangement, compressing the wound arrangement, and packing it into a pouch. The method yet further includes soaking the wound arrangement in an electrolyte for a predetermined time and at a predetermined temperature. The electrolyte includes a lithium hexafluorophosphate salt dissolved in a solvent including ethylene carbonate and diethylene carbonate in about a 1:2 volume ratio. The additive includes fluoroethylene carbonate in an 8-12% weight ratio.
1. A battery comprising:
an anode, wherein the anode comprises silicon monoxide (SiO);
a cathode, wherein the cathode comprises lithium cobalt oxide (LCO);
a separator, wherein the separator comprises an electrically-insulating material;
a solid electrolyte interphase (SEI) layer, wherein the SEI layer comprises at least one of: lithium carbonate (Li 2 CO 3 ) or lithium oxide (Li 2 O); and
an electrolyte, wherein the electrolyte comprises a salt dissolved in a solvent and at least one additive, wherein the salt comprises lithium hexafluorophosphate (LiPF 6 ), wherein the solvent comprises ethylene carbonate (EC) and diethylene carbonate (DEC) in about a 1:2 volume ratio, and wherein the additive comprises fluoroethylene carbonate (FEC) in an 8-12% weight ratio wherein the solid electrolyte interphase layer is between the electrolyte and a surface of the anode.
2. The battery of claim 1 , wherein the lithium hexafluorophosphate (LiPF 6 ) is dissolved in the solvent with a 1.1-1.3 (mol/L) molar concentration.
3. The battery of claim 1 , wherein the at least one additive further comprises at least one of: propylene carbonate (PC) in a 6-9% weight ratio, propylsultone (PS) in a 3-4% weight ratio, or fluorobenzene (FB) in a 3-5% weight ratio.
4. The battery of claim 1 , wherein the additives further comprises succinonitrile (SN) in a 1-3% weight ratio.
5. The battery of claim 1 , wherein the anode, the cathode, and the separator are disposed in a layered arrangement.
6. The battery of claim 5 , wherein the layered arrangement is wound so as to form a jelly-roll configuration.
7. The battery of claim 6 , wherein the jelly-roll configuration is packaged within a pouch.
8. The battery of claim 7 , wherein, subsequent to an initial cell formation cycle, a thickness of the pouch does not increase more than 8% over a two week storage period.