Methods of forming polycrystalline diamond with liquid hydrocarbons and hydrates thereof
View Patent ↗Methods of forming polycrystalline diamond include encapsulating diamond particles and a hydrocarbon substance in a canister, and subjecting the encapsulated diamond particles and hydrocarbon substance to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles. Cutting elements for use in an earth-boring tool includes a polycrystalline diamond material formed by such processes. Earth-boring tools include such cutting elements.
1. A method of forming polycrystalline diamond, comprising:
encapsulating diamond particles and a liquid hydrocarbon substance in a canister; and
after encapsulating the diamond particles and the liquid hydrocarbon substance in the canister, subjecting the encapsulated diamond particles and the liquid hydrocarbon substance to a pressure of at least 5.0 GPa and a temperature of at least 1,400° C. to form direct diamond-to-diamond inter-granular bonds between the diamond particles.
2. The method of claim 1 , wherein encapsulating the diamond particles and the liquid hydrocarbon substance in the canister comprises:
placing the diamond particles in the canister;
placing the liquid hydrocarbon substance in the canister with the diamond particles; and
sealing the canister with the diamond particles and the liquid hydrocarbon substance therein.
3. The method of claim 1 , wherein subjecting the encapsulated diamond particles and the liquid hydrocarbon substance to a pressure of at least 5.0 GPa and a temperature of at least 1,400° C. to form direct diamond-to-diamond inter-granular bonds between the diamond particles comprises dissociating at least some of the liquid hydrocarbon substance to form carbon and bonding at least some of the carbon with the diamond particles.
4. The method of claim 1 , wherein encapsulating diamond particles and a liquid hydrocarbon substance in the canister comprises encapsulating diamond nanoparticles and the liquid hydrocarbon substance in the canister.
5. The method of claim 1 , wherein encapsulating diamond particles and a liquid hydrocarbon substance in the canister comprises encapsulating diamond particles having a multimodal grain size distribution and the liquid hydrocarbon substance in the canister.
6. The method of claim 1 , wherein encapsulating diamond particles and a liquid hydrocarbon substance in the canister comprises encapsulating diamond particles and a liquid hydrocarbon substance selected from the group consisting of methane, ethane, propane, butane, pentane, hexane, heptane, and octane.
7. The method of claim 6 , wherein encapsulating diamond particles and a liquid hydrocarbon substance in the canister comprises encapsulating diamond particles and methane in the canister.
8. A method of forming polycrystalline diamond, comprising:
placing diamond particles in a canister;
placing a liquid hydrocarbon substance in the canister with the diamond particles;
sealing the canister with the diamond particles and the liquid hydrocarbon substance therein at a temperature of about −150° C. or less; and
after sealing the canister, subjecting the diamond particles and the liquid hydrocarbon substance in the canister to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles.
9. The method of claim 8 , wherein sealing the canister at a temperature of about −150° C. or less comprises sealing the canister at a temperature of about −182° C. or less.
10. The method of claim 8 , wherein subjecting the diamond particles and the liquid hydrocarbon substance in the canister to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles comprises subjecting the diamond particles and the liquid hydrocarbon substance in the canister to a pressure of at least 5.0 GPa and a temperature of at least 1,400° C.
11. A method of forming polycrystalline diamond, comprising:
sealing a canister with diamond particles and a hydrated hydrocarbon therein; and
subjecting the diamond particles and the hydrated hydrocarbon in the canister to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles.
12. The method of claim 11 , wherein subjecting the diamond particles and the hydrated hydrocarbon in the canister to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles comprises subjecting the diamond particles and the hydrated hydrocarbon in the canister to a pressure of at least 5.0 GPa and a temperature of at least 1,400° C.
13. The method of claim 11 , further comprising selecting the hydrated hydrocarbon to comprise at least one hydrocarbon selected from the group consisting of methane hydrate and ethane hydrate.
14. The method of claim 11 , further comprising placing the hydrated hydrocarbon in the canister at a temperature below room temperature.
15. The method of claim 14 , wherein placing the hydrated hydrocarbon in the canister at a temperature below room temperature comprises placing the hydrated hydrocarbon in the canister at a temperature of about −150° C. or less.
16. The method of claim 15 , wherein placing the hydrated hydrocarbon in the canister at a temperature of about −150° C. or less comprises placing the hydrated hydrocarbon in the canister at a temperature of about −182° C. or less.
17. The method of claim 16 , wherein subjecting the diamond particles and the hydrated hydrocarbon in the canister to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles comprises dissociating at least some of the hydrocarbon to form carbon and bonding at least some of the carbon with the diamond particles.
18. A method of forming polycrystalline diamond, comprising:
encapsulating diamond particles and methane hydrate in a canister; and
subjecting the encapsulated diamond particles and the methane hydrate to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles.
19. The method of claim 18 , wherein encapsulating diamond particles and methane hydrate in the canister comprises encapsulating diamond nanoparticles and the methane hydrate in the canister.
20. The method of claim 18 , wherein subjecting the encapsulated diamond particles and the methane hydrate to a pressure and a temperature sufficient to form inter-granular bonds between the diamond particles comprises dissociating at least some of the methane hydrate to form carbon and bonding at least some of the carbon with the diamond particles.