Anode active material for lithium secondary battery and preparation thereof
View Patent ↗The present invention relates to an anode active material for a lithium secondary battery, comprising a carbon material, and a coating layer formed on the surface of particles of the carbon material and having a plurality of Sn-based domains having an average diameter of 1 μm or less. The inventive anode active material having a Sn-based domains coating layer on the surface of a carbon material can surprisingly prevent stress due to volume expansion which generates by an alloy of Sn and lithium. Also, the inventive method for preparing an anode active material can easily control the thickness of the coating layer.
1. A method for preparing an anode active material for a lithium secondary battery, the method comprising:
dispersing a carbon material in an electroplating electrolyte of an electroplating bath, wherein the electroplating bath includes a main electrode and a counter electrode disposed therein; and then
applying an electric current to form a coating layer having a plurality of Sn-based domains having an average diameter of 1 μm or less on the surface of particles of the carbon material, wherein the electric current is a pulse current ranging from 0.1 A to 10 A; and
stirring the electrolyte at a speed ranging from 800 to 900 rpm while the electric current is applied,
wherein the anode active material comprises the particles of the carbon material having the coating layer formed on the surface thereof,
wherein the Sn-based domains have a hemisphere shape and/or agglomeration of several hemispheres,
wherein the Sn-based domains are of an Sn alloy and wherein the Sn alloy is an alloy of Sn and a metal selected from the group consisting of Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Pd, Ag, Cd, In, Sb, Pt, Au, Hg, Pb and Bi, and
wherein the coating layer has a density of 2.2 to 5.9 g·cm −3 .
2. The method according to claim 1 , wherein the electroplating electrolyte is an acid-based Ni—Sn, Sn—Zn, Sn—Co or Sn—Pb plating solution; a sulfate-based Sn plating solution; hydrochloride-based Sn plating solution; a sulfonate-based Sn, Sn—Pb or Sn—Bi plating solution; a cyanide-based Sn—Cu or Sn—Ag plating solution; or a pyrophosphate-based Sn, Sn—Cu, Sn—Pb or Sn—Zn plating solution.
3. The method according to claim 1 , wherein the carbon material is selected from the group consisting of natural graphite, artificial graphite, mesocarbon microbeads (MCMB), carbon fibers, carbon black and a mixture thereof.
4. The method according to claim 1 , wherein the carbon material has a specific surface area 10 m 2 /g or less.
5. The method according to claim 1 , wherein the carbon material has an average particle size of 5 to 100 μm.