HIGH ENERGY CATHODE MATERIAL
A method for synthesizing high voltage active materials using a process control agent. The process control agent may be a carbon source. The active material may be a spinel.
1 . A method for producing an active material for use in a lithium ion battery, comprising:
providing a lithium precursor, a transition metal precursor, and a process control agent;
milling the lithium precursor, the transition metal precursor, and the process control agent to form a milled powder; and
heating the milled powder for a time and temperature to form the active material.
2 . The method of claim 1 wherein the process control agent comprises a carbon source.
3 . The method of claim 2 wherein the carbon source comprises carbon black.
4 . The method of claim 2 wherein the carbon source comprises graphite.
5 . The method of claim 2 wherein the carbon source comprises an ethylene oxide polymer.
6 . The method of claim 2 wherein the carbon source comprises poly(ethylene oxide).
7 . The method of claim 1 wherein the heating is performed for a time less than 12 hours.
8 . The method of claim 1 wherein the heating is performed for a time less than 1 hour.
9 . The method of claim 1 wherein the heating is performed for a time of about 0.5 hour.
10 . The method of claim 1 wherein the heating is performed at a temperature of at least 500 degrees Celsius.
11 . The method of claim 1 wherein the heating is performed at a temperature of at least 700 degrees Celsius.
12 . The method of claim 1 wherein the heating is performed at a temperature of at least 900 degrees Celsius.
13 . The method of claim 1 wherein the milled powder contains unreacted process control agent.
14 . The method of claim 13 wherein the heating consumes substantially all of the unreacted process control agent.
15 . The method of claim 1 wherein the transition metal precursor comprises manganese.
16 . The method of claim 1 further comprising an additional transition metal precursor.
17 . The method of claim 16 wherein the additional transition metal precursor comprises nickel.
18 . The method of claim 17 wherein the active material comprises LiMn 1.5 Ni 0.5 O 4 .