Process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst
Provided are a complex prepared from ammonium salt-containing ligands and having such an equilibrium structural formula that the metal center takes a negative charge of 2 or higher, and a method for preparing polycarbonate via copolymerization of an epoxide compound and carbon dioxide using the complex as a catalyst. When the complex is used as a catalyst for copolymerizing an epoxide compound and carbon dioxide, it shows high activity and high selectivity and provides high-molecular weight polycarbonate, and thus easily applicable to commercial processes. In addition, after forming polycarbonate via carbon dioxide/epoxide copolymerization using the complex as a catalyst, the catalyst may be separately recovered from the copolymer.
1. A method for preparing polycarbonate, comprising carrying out copolymerization of an epoxide compound with carbon dioxide using a complex represented by Chemical Formula 6:
wherein
A 1 and A 2 independently represent an oxygen or sulfur atom;
Xb and Xc independently represents 2,4-dinitrophenolate or BF 4 − ;
R 62 and R 64 are independently selected from tert-butyl, methyl, ethyl, isopropyl and hydrogen, and R 61 and R 63 independently represent —[CH{(CH 2 ) 3 N + Bu 3 } 2 ] or —[CMe{(CH 2 ) 3 N + Bu 3 } 2 ];
b+c−1 represents 4; and
A 3 represents —CH═N-Q-N═CH— and Q represents trans-1,2-cyclohexylene or ethylene as a catalyst.
2. The method according to claim 1 , wherein the epoxide compound is selected from the group consisting of (C2-C20) alkylene oxide substituted or unsubstituted by a halogen or alkoxy; (C4-C20) cycloalkylene oxide substituted or unsubstituted by a halogen or alkoxy; and (C8-C20) styrene oxide substituted or unsubstituted by a halogen, alkoxy, alkyl or aryl.
3. A method for preparing polycarbonate, comprising carrying out copolymerization of an epoxide compound with carbon dioxide using a complex represented by Chemical Formula 6:
wherein
A 1 and A 2 independently represent an oxygen or sulfur atom;
one of Xb and Xc represents BF 4 − , two of them represent 2,4-dinitrophenolate, and the remaining two are anions represented by Chemical Formula 10;
R 62 and R 64 are independently selected from tert-butyl, methyl, ethyl, isopropyl and hydrogen, and R 61 and R 63 independently represent —[CH{(CH 2 ) 3 N + Bu 3 } 2 ] or —[CMe{(CH 2 ) 3 N + Bu 3 } 2 ];
b+c−1 represents 4; and
A 3 represents —CH═N-Q-N═CH— and Q represents trans-1,2-cyclohexylene or ethylene as a catalyst,
[Chemical Formula 10]
wherein
R represents methyl or H.