Anode and secondary battery with anode material with pore group with low volumetric capacity
View Patent ↗A battery capable of improving cycle characteristics is provided. An anode includes: an anode current collector, and an anode active material layer arranged on the anode current collector, in which the anode active material layer includes an anode active material including silicon (Si), and including a pore group with a diameter ranging from 3 nm to 50 nm both inclusive, and the volumetric capacity per unit weight of silicon of the pore group with a diameter ranging from 3 nm to 50 nm both inclusive is 0.2 cm 3 /g or less, the volumetric capacity being measured by mercury porosimetry using a mercury porosimeter.
1. A secondary battery comprising a cathode, an anode and an electrolytic solution, wherein:
the anode includes an anode current collector, and an anode active material layer on a surface of the anode current collector;
the anode active material layer includes active material comprising (a) silicon and (b) pores with diameters ranging from 3 nm to 50 nm; and
a volumetric capacity per unit of silicon of the pores with diameters distributed over a range from 3 nm to 50 nm is 0.2 cm 3 /g or less as measured by mercury porosimetry using a mercury porosimeter.
2. The secondary battery according to claim 1 , wherein the volumetric capacity per unit weight of silicon of the pores with diameters distributed over the range from 3 nm to 50 nm is 0.05 cm 3 /g or less.
3. The secondary battery according to claim 1 , wherein the volumetric capacity per unit weight of silicon of the pores with diameters distributed over the range from 3 nm to 50 nm is 0 cm 3 /g.
4. The secondary battery according to claim 1 , wherein:
a volumetric capacity per unit weight of silicon of those pores with diameters distributed over a range from 3 nm to 20 nm is 0.2 cm 3 /g or less.
5. The secondary battery according to claim 1 , wherein a volumetric capacity per unit of weight of silicon of those pores with diameters distributed over the range from 3 nm to 20 nm is 0.05 cm 3 /g or less.
6. The secondary battery according to claim 1 , wherein a volumetric capacity per unit of silicon of those pores of those pores with diameters distributed over the range from 3 nm to 20 nm is 0 cm 3 /g.
7. The secondary battery according to claim 1 , wherein the anode active material layer is comprised of a plurality of particles.
8. The secondary battery according to claim 7 , wherein the anode active material layer has a multilayer configuration.
9. The secondary battery according to claim 1 , wherein the anode active material layer is formed by a vapor-phase method.
10. The secondary battery according to claim 1 , wherein the anode active material layer includes oxygen, and a content of the oxygen in the anode active material layer is within a range from 3 at % to 40 at %.
11. The secondary battery according to claim 1 , wherein the anode active material layer includes at least one metal element selected from the group consisting of iron, cobalt, nickel, chromium, titanium, and molybdenum.
12. The secondary battery according to claim 1 , wherein the anode active material layer includes an oxygen-containing region extending in a thickness direction of the anode active material layer, and the oxygen content in the oxygen-containing region is higher than the oxygen content in a region other than the oxygen-containing region.
13. The secondary battery according to claim 1 , wherein a ten-point height of a roughness profile Rz of the surface of the anode current collector is within a range from and including 1.5 μm to 6.5 μm.
14. The secondary battery according to claim 1 , wherein the electrolytic solution includes a solvent including a fluorinated carbonate.
15. The secondary battery according to claim 14 , wherein the fluorinated carbonate is difluoroethylene carbonate.
16. The secondary battery according to claim 1 , wherein the electrolytic solution includes an electrolyte salt including boron and fluorine.
17. The secondary battery according to claim 16 , wherein the electrolyte salt is lithium tetrafluoroborate.
18. The secondary battery according to claim 1 , wherein the cathode, the anode and the electrolytic solution are contained in a cylindrical or prismatic package member.
19. The secondary battery according to claim 18 , wherein the package member includes iron or an iron alloy.
20. An anode comprising an anode current collector, and an anode active material layer on the anode current collector, wherein:
the anode active material layer includes active material comprising (a) silicon and (b) pores with diameters ranging from 3 nm to 50 nm; and
a volumetric capacity per unit of silicon of the pores with diameters distributed over a range from 3 nm to 50 nm is 0.2 cm 3 /g or less as measured by mercury porosimetry using a mercury porosimeter.