IP Library Granted Patent US 10,241,245
Granted Patent B2
US 10,241,245 · App. 14/951,687 · Granted Mar 26, 2019

Optical filter and method for manufacturing optical filter

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Quick Facts
Patent No.
US 10,241,245
App. No.
14/951,687
Granted
Mar 26, 2019
Kind
B2
Abstract

There are provided an optical filter excellent in weather resistance and a method for manufacturing an optical filter. The optical filter of the present invention includes a transparent substrate, and an optical multilayer film provided on a surface of the transparent substrate. In the optical multilayer film, a low-refractive index film containing silicon oxide (SiO 2 ) and a high-refractive index film higher in refractive index than the low-refractive index film are alternately stacked. A density of a portion of the low-refractive index film close to an interface between the low-refractive index film and the high-refractive index film is lower than a density of a portion of the low-refractive index film other than the portion close to the interface.

Claims (25)

1. An optical filter, comprising:

a transparent substrate; and

an optical multilayer film formed on a surface of the transparent substrate and comprising a low-refractive index film and a high-refractive index film such that the low-refractive index film and the high-refractive index film are alternately stacked,

wherein the high-refractive index film is higher in refractive index than the low-refractive index film, and the low-refractive index film includes silicon oxide and has a low density portion formed closer to an interface between the low-refractive index film and the high-refractive index film than a middle portion of the low-refractive index film such that a density of the low density portion is lower than a density of the middle portion of the low-refractive index film.

2. The optical filter according to claim 1 , wherein the low-refractive index film comprises a first low-refractive index film stacked on the high-refractive index film and forming the low density portion and a second low-refractive index film stacked on the first low-refractive index film and forming the middle portion higher in density than the first low-refractive index film.

3. The optical filter according to claim 2 , wherein the first low-refractive index film has a physical film thickness of 3 nm or more and equal to or lower than half a physical film thickness of the low-refractive index film.

4. The optical filter according to claim 2 , wherein the transparent substrate is fluorophosphoric acid glass.

5. The optical filter according to claim 1 , wherein the low-refractive index film becomes higher in density with increasing distance from the interface with the high-refractive index film in a direction vertical to the surface of the transparent substrate.

6. The optical filter according to claim 5 , wherein the transparent substrate is fluorophosphoric acid glass.

7. The optical filter according to claim 1 , wherein the high-refractive index film includes an oxide material selected from the group consisting of titanium, niobium, and tantalum.

8. The optical filter according to claim 7 , wherein the low-refractive index film comprises a first low-refractive index film stacked on the high-refractive index film and forming the low density portion and a second low-refractive index film stacked on the first low-refractive index film and forming the middle portion higher in density than the first low-refractive index film.

9. The optical filter according to claim 8 , wherein the first low-refractive index film has a physical film thickness of 3 nm or more and equal to or lower than half a physical film thickness of the low-refractive index film.

10. The optical filter according to claim 7 , wherein the low-refractive index film becomes higher in density with increasing distance from the interface with the high-refractive index film in a direction vertical to the surface of the transparent substrate.

11. The optical filter according to claim 7 , wherein the transparent substrate is fluorophosphoric acid glass.

12. The optical filter according to claim 1 , wherein the optical multilayer film is formed by vacuum deposition.

13. A near-infrared cut filter, comprising the optical filter of claim 1 .

14. The optical filter according to claim 1 , wherein the transparent substrate is fluorophosphoric acid glass.

15. A method for manufacturing an optical filter, comprising:

forming an optical multilayer film on a surface of a transparent substrate by alternately stacking a low-refractive index film and a high-refractive index film,

wherein the high-refractive index film is higher in refractive index than the low-refractive index film, and the forming comprises forming the low-refractive index film such that the low-refractive index film includes silicon oxide and has a low density portion formed closer to an interface between the low-refractive index film and the high-refractive index film than a middle portion of the low-refractive index film and that a density of the low density portion is lower than a density of the middle portion of the low-refractive index film.

16. The method for manufacturing an optical filter according to claim 15 , wherein the forming comprises stacking a first low-refractive index film forming the low density portion on the high-refractive index film and stacking a second low-refractive index film forming the middle portion higher in density than the first low-refractive index film, on the first low-refractive index film.

17. The method for manufacturing an optical filter according to claim 15 , wherein the forming comprises forming the low-refractive index film such that the low-refractive index film becomes higher in density with increasing distance from the interface with the high-refractive index film in a direction vertical to the surface of the transparent substrate.

18. The method for manufacturing an optical filter according to claim 15 , wherein the forming comprises controlling a degree of vacuum in a film forming chamber such that the density of the low-refractive index film is controlled.

19. The method for manufacturing an optical filter according to claim 18 , wherein the forming comprises controlling a flow rate of an oxygen gas to be introduced into the film forming chamber such that the density of the low-refractive index film is controlled.

20. The method for manufacturing an optical filter according to claim 15 , wherein the forming comprises forming the optical multilayer film by vacuum deposition.

Assignments (2)
CHANGE OF NAME Recorded Aug 7, 2018
From: ASAHI GLASS COMPANY, LIMITED
To: AGC INC.
Reel/Frame 046730/0786 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 25, 2015
From: TATEMURA, MITSUYUKI; SAKURAI, AKINORI; NAOE, TADANARI
To: ASAHI GLASS COMPANY, LIMITED
Reel/Frame 037140/0946 →