Fabricating method of lithium electrode and lithium secondary battery including the same
View Patent ↗The present invention provides a fabricating method of a lithium electrode, a lithium electrode, and a lithium secondary battery including the same, the fabricating method including: a) forming an active material layer on one surface or active material layers on both surfaces of a current collector; b) forming a conductive fiber structure layer in a frame form on a surface of the active material layer; and c) pressing the current collector on which the conductive fiber structure layer in a frame form is formed. Since breakage of the active materials caused by pressing is prevented by the conductive fiber structure layer in a frame form, the present invention provides a lithium electrode capable of maintaining electronic conductivity between active material particles and having a long lifespan and high-rate charge and discharge characteristics.
1. A fabricating method of a lithium electrode, comprising:
a) forming an active material layer on one surface or active material layers on both surfaces of a current collector;
b) forming a conductive fiber structure layer in a frame form on a surface of the active material layer; and
c) pressing the current collector on which the conductive fiber structure layer in a frame form is formed,
wherein the active material layer of step a) is formed by applying and drying a slurry including active electrode active materials, a conductive material, a binder, and a solvent.
2. The fabricating method of claim 1 , wherein the conductive fiber structure layer of step b) is formed by applying and drying a slurry including a fibrous conductive material.
3. The fabricating method of claim 2 , wherein the fibrous conductive material is a carbon nanotube or a carbon nanofiber having a diameter of 10 to 200 nm, a length of 3 to 100 μm, and a surface area of 20 to 200 m 2 /g.
4. The fabricating method of claim 2 , wherein the slurry including the fibrous conductive material further includes at least one particulate conductive material selected from the group consisting of carbon-based conductive materials, electrode active materials, transition metal oxides and phosphate-based transition metal oxides.
5. The fabricating method of claim 4 , wherein the carbon-based conductive material includes one selected from the group consisting of graphite, acetylene black, carbon black, Ketjen black, channel black, furnace black, lamp black, thermal black and carbon fluoride, or mixtures of two or more thereof.
6. The fabricating method of claim 1 , wherein the pressing of step c) is performed by high densification with a pressure of 10 kg/cm 2 to 100 ton/cm 2 using a roll press or a plate press.
7. A lithium electrode fabricated by the fabricating method of claim 1 .
8. A lithium secondary battery comprising the lithium electrode of claim 7 .