Hierarchically structured carbon nanotube articles and methods for production thereof
The present invention provides, in one embodiment, a nanostructured article. In an embodiment, the nanostructured article includes a first material made from a plurality of intermingled nanotubes placed on top of one another to form a continuous structure with sufficient structural integrity to be handled. The nanostructured article can also include a second material made from a plurality of nanotubes forming a layer situated on a surface of the first material. The second material, in an embodiment, has a nanotube density lower than the nanotube density of the first material. The nanostructured article further a layer of ordered pyrolytic carbon between the first material and the second material to enhance the bond and structural integrity between the first material and the second material, as well as enhancing the electrical and thermal conductivity between the first and second materials. A process for forming the nanostructured article is also provided.
1. A nanostructured article comprising:
a first material made from a plurality of non-aligned intermingled nanotubes placed on top of one another to form a continuous structure with sufficient structural integrity to be handled wherein the first material has a nanotube density ranging from about 0.75 g/cc to about 1.5 g/cc;
a second material made from a plurality of nanotubes and forming a layer situated on a surface of the first material, wherein the second material has a nanotube density ranging from about 0.1 g/cc to about 0.5 g/cc and pores ranging from about 0.1 micron to about 10 microns; and
a layer of ordered pyrolytic carbon between the first material and the second material to enhance the bond and structural integrity between the first material and the second material.
2. The article as set forth in claim 1 , wherein the first material includes one of a non-woven sheet or a yarn.
3. The article as set forth in claim 1 , wherein the first material has an electrical conductivity ranging from about 1 S/m to about 10E6 S/m or greater.
4. The article as set forth in claim 1 , wherein the first material has a tensile strength of greater than about 1 N/tex.
5. The article as set forth in claim 1 , wherein the second material has an electrical conductivity ranging from about 2 S/m to about 5E5 S/m.