FCVD line bending resolution by deposition modulation
A method of reducing line bending and surface roughness of a substrate with pillars includes forming a treated surface by treating a pillar-containing substrate with a radical. The radical may be silicon-based, nitrogen-based or oxygen-based. The method may include forming a dielectric film over the treated surface by reacting an organosilicon precursor and an oxygen precursor. The method may include curing the dielectric film at a temperature of about 150° C. or less. A method of reducing line bending and surface roughness of a substrate with pillars includes forming a dielectric film over a pillar-containing substrate by reacting an organosilicon precursor, an oxygen precursor, and a radical precursor. The method may include curing the dielectric film at a temperature of about 150° C. or less. The radical precursor may be selected from the group consisting of nitrogen-based radical precursor, oxygen-based radical precursor, and silicon-based radical precursor.
1. A method of reducing line bending and surface roughness of a substrate with pillars, comprising:
forming first radicals and ions in a remote plasma system that is a radical source;
controlling flow of ions toward the pillar-containing substrate via a radical distribution plate configured to filter ions;
forming second radicals in a dual-channel showerhead, wherein the first radicals and the second radicals are independently silicon-based, nitrogen-based or oxygen-based;
forming a treated surface by treating the pillar-containing substrate with the first radicals and the second radicals;
forming a dielectric film over the pillar-containing substrate by reacting an organosilicon precursor, an oxygen precursor, and at least one of the first and second radicals at a temperature of about 100° C. or less at a pressure between about 0.5 Torr and about 10 Torr, wherein the organosilicon precursor is introduced into a processing region at a flow rate between about 10 sccm and about 1800 sccm, the oxygen precursor is introduced into the processing region at a flow rate between about 10 mgm and about 1,500 mgm, and a radical precursor is introduced to the radical source at a flow rate between about 600 sccm and about 1,250 sccm; and
curing the dielectric film at a temperature of about 150° C. or less, wherein the radical precursor is selected from the group consisting of nitrogen-based radical precursor, oxygen-based radical precursor, and silicon-based radical precursor.
2. The method of claim 1 , wherein the organosilicon precursor is selected from the group consisting of triethoxysiloxane, tetramethoxysiloxane, trimethoxysiloxane, hexamethoxydisiloxane, octamethoxytrisiloxane, and octamethoxydodecasiloxane.
3. The method of claim 1 , wherein the organosilicon precursor is a silazoxane selected from the group consisting of hexamethoxydisilazoxane, methyl hexamethoxydisilazoxane, chlorohexamethoxydisilazoxane, hexaethoxydi-silazoxane, nonamethoxytrisilazoxane, and octamethoxycyclosilazoxane.
4. The method of claim 1 , wherein the organosilicon precursor is a halogenated siloxane selected from the group consisting of tetrachlorosilane, dichlorodiethoxysiloxane, chlorotriethoxysiloxane, hexachlorodisiloxane, and octachlorotrisiloxane.
5. The method of claim 1 , wherein the organosilicon precursor is an aminosilane selected from the group consisting of trisilylamine, hexamethyldisilazane, silatrane, tetrakis(dimethylamino)silane, bis(diethylamino)-silane, tris(dimethylamino)chlorosilane, and metylsilatrane.
6. The method of claim 1 , wherein the organosilicon precursor is a disilane selected from the group consisting of alkoxy disilanes, alkoxy-alkyl disilanes, and alkoxy-acetoxy disilanes, consisting of compounds having the general structure
where R 1 -R 6 may be, independently, a C 1-3 alkoxy group, a C 1-3 alkyl group, or an acetoxy group, wherein at least one of R 1-6 is an alkoxy group or an acetoxy group.
7. The method of claim 1 , wherein the organosilicon precursor is a cyclic silane selected from the group consisting of octamethyl-1,4-dioxa-2,3,5,6-tetrasilacyclohexane, 1,4-dioxa-2,3,5,6-tetrasilzcyclohexane, and 1,2,3,4,5,6-hexamethoxy-1,2,3,4,5,6-hexamethylcyclohexasilane, cyclobutasilane, cyclo-pentasilane, cyclohexasilane, cycloheptasilane, and cyclooctasilane.
8. The method of claim 1 , wherein the oxygen precursor is selected from the group consisting of oxygen, ozone, NO, NO 2 , N 2 O, water, peroxide, carbon monoxide and carbon dioxide.
9. The method of claim 1 , wherein the organosilicon precursor, the oxygen precursor, and the at least one of the first and second radicals are reacted at a temperature of about 65° C.
10. The method of claim 1 , wherein the ratio of the flow rate of the organosilicon precursor to the flow rate of the radical precursor is between about 1:1 and about 10:1.
11. The method of claim 1 , wherein the radical precursor is a silicon-based radical precursor and is selected from the group consisting of (dimethylsilyl)(trimethylsilyl)methane, hexamethyldisilane, trimethylsilane, trimethylsilylchloride, tetramethylsilane, tetraethoxysilane, tetramethoxysilane, tetrakis-(trimethylsilyl)silane, (dimethylamino)dimethylsilane, dimethyldiethoxysilane, dimethyldimethoxysilane, methyltrimethoxysilane, dimethoxytetramethyl-disiloxane, tris(dimethylamino)silane, bis(dimethylamino)methylsilane, and disiloxane.
12. The method of claim 1 , wherein the radical precursor is an oxygen-based radical precursor and is selected from the group consisting of oxygen, H 2 O, and hydrogen peroxide.
13. The method of claim 1 , wherein the radical precursor is ammonia.