Lithium secondary battery
View Patent ↗Disclosed is a lithium secondary battery, including a cathode, an anode and a non-aqueous electrolyte, wherein the cathode includes a cathode active material containing lithium-metal oxide of which at least one of metals has a concentration gradient region between a core part and a surface part thereof, and the non-aqueous electrolyte includes a lithium salt, a polyfunctional nitrile compound and an organic solvent, such that the high-temperature storage and lifespan properties may be improved.
1. A lithium secondary battery, comprising a cathode, an anode and a non-aqueous electrolyte,
wherein the cathode includes a cathode active material containing a lithium-metal oxide containing Ni, Co, and Mn, and having the Formula 1 below:
Li x M1 a M2 b M3 c O y , Formula 1
wherein M1, M2 and M3 are Ni, Co, and Mn, respectively, and
0<x≤1.1, 2≤y≤2.02, 0<a≤1, 0<b≤1, 0<c≤1, and 0<a+b+c≤1,
wherein the non-aqueous electrolyte includes a lithium salt, a polyfunctional nitrile compound and an organic solvent,
wherein the cathode active material has regions comprising:
a core part;
a surface part; and
an intermediate region between the core part and the surface part, the intermediate region comprising a concentration gradient region wherein at least one of Ni, Co, and Mn has a decreasing or increasing concentration gradient in a direction from the core part to the surface part, and a non-concentration gradient region wherein Ni, Co, and Mn do not have a concentration gradient in a direction from the core part to the surface part, and
wherein the non-concentration gradient region is formed between the core part and the concentration gradient region, and between the concentration gradient region and the surface part.
2. The lithium secondary battery according to claim 1 , wherein the concentration of Mn is increased within the concentration gradient region in the direction from the core part to the surface part, and the concentration of Ni is decreased within the concentration gradient region in the direction from the core part to the surface part.
3. The lithium secondary battery according to claim 1 , wherein Co has a constant concentration throughout the cathode active material from the core part to the surface part.
4. The lithium secondary battery according to claim 1 , wherein 0.6≤a≤0.95 and 0.05≤b+c≤0.4.
5. The lithium secondary battery according to claim 1 , wherein 0.7≤a≤0.9 and 0.1≤b+c≤0.3.
6. The lithium secondary battery according to claim 1 , wherein the lithium-metal oxide has a primary particle of a rod-type shape.
7. The lithium secondary battery according to claim 1 , wherein the polyfunctional nitrile compound is a dinitrile compound, trinitrile compound or a mixture thereof.
8. The lithium secondary battery according to claim 1 , wherein the polyfunctional nitrile compound is at least one selected from a group consisting of succinonitrile, sebaconitrile, glutaronitrile, adiponitrile, 1,5-dicyanopentane, 1,6-dicyanohexane, 1,7-dicyanoheptane, 1,8-dicyanooctane, 1,9-dicyanononane, 1,10-dicycathodecane, 1,12-dicyanododecane, tetramethyl succinonitrile, 2-methyl glutaronitrile, 2,4-dimethyl glutaronitrile, 2,2,4,4-tetramethyl glutaronitrile, 1,4-dicyanopentane, 2,5-dimethyl-2,5-hexane dicarbonitrile, 2,6-dicyanoheptane, 2,7-dicyanooctane, 2,8-dicyanononane, 1,6-dicycathodecane, 1,3,5-hexane tricarbonitrile and 1,3,6-hexane tricarbonitrile.
9. The lithium secondary battery according to claim 1 , wherein the polyfunctional nitrile compound is at least one selected from a group consisting of succinonitrile, glutaronitrile, adiponitrile, 1,3,5-hexane tricarbonitrile and 1,3,6-hexane tricarbonitrile.
10. The lithium secondary battery according to claim 1 , wherein the polyfunctional nitrile compound is included in an amount of 0.1 to 10% by weight to 100% by weight of a whole non-aqueous electrolyte.
11. The lithium secondary battery according to claim 1 , wherein the polyfunctional nitrile compound is included in an amount of 0.5 to 7% by weight to 100% by weight of a whole non-aqueous electrolyte.
12. The lithium secondary battery according to claim 1 , wherein the polyfunctional nitrile compound is included in an amount of 1 to 7% by weight to 100% by weight of a whole non-aqueous electrolyte.
13. The lithium secondary battery according to claim 1 , wherein a charge voltage ranges from 4.2 to 4.5V.
14. The lithium secondary battery according to claim 1 , wherein a charge voltage ranges from 4.2 to 4.4V.
15. The lithium secondary battery according to claim 1 , wherein a charge voltage ranges from 4.2 to 4.3V.