Method for the separation of metal ions that are divalent or higher from strong acids or highly acidic media
View Patent ↗The present invention relates to a method of purifying strong acids or strongly acidic media to remove di- and higher valent metal ions, which can be used within the context of the production of high-purity silica. The invention further relates to the use of special ion exchangers for carrying out the method according to the invention and the resultant high-purity silicas.
1. A method of producing high-purity silica, the method comprising:
(a) producing a preparation from an acidifying agent or an acidifying agent and water with a pH of less than 2;
(b) preparing a silicate solution with a viscosity from 0.1 to 10000 poise;
(c) adding the silicate solution from step (b), to the preparation from step (a) thereby forming a precipitate suspension comprising a liquid phase and precipitated silica, where the pH of the resultant precipitate suspension always remains at a value less than 2;
(d) separating and washing the silica with a washing medium having a pH of less than 2;
(e) neutral washing the silica with deionized water; and
(f) drying the silica;
wherein at least one aminomethylphosphonic acid ion exchanger is brought in contact, for the purpose of ion exchange, with the liquid phase of the precipitate suspension during precipitation of the silica within step (c), or with the washing medium within step (d), or with both,
and wherein the ion exchanger is regenerated with an alkaline solution comprising tartrate.
2. The method according to claim 1 , wherein the liquid phase of the precipitate suspension during precipitation of the silica within step (c), or of the washing medium within step (d), or both, which is brought in contact with at least one aminomethylphosphonic acid ion exchanger, is circulated by pump or is moved in order to improve ion exchange.
3. The method according to claim 1 , wherein the acidifying agent contained in the preparation comprises sulphuric acid.
4. The method according to claim 1 , wherein the ion exchange with the aminomethylphosphonic acid ion exchanger takes place in parallel with the production of the high-purity silica or within the timeframe of the production process.
5. The method according to claim 1 , wherein the production of the high-purity silica is a continuous or a discontinuous process.
6. The method according to claim 1 , wherein regeneration of the aminomethylphosphonic acid ion exchanger occurs in parallel with the production of the high-purity silica.
7. The method according to claim 1 , wherein the liquid phase of the precipitate suspension during precipitation of the silica within step (c), or the washing medium within step (d), or both, are purified through the use of an acid retardation process.