POLYOXYMETHYLENE COPOLYMER SUITED FOR USE IN LIQUID SYSTEMS
A water soluble polyoxymethylene copolymer is described. In one embodiment, the polyoxymethylene copolymer is a liquid at 35° C. and is water soluble. The polyoxymethylene copolymer may have a comonomer content of greater than about 60% by weight, such as greater than about 70% by weight, such as greater than about 80% by weight. The copolymer is usually formed using a chain transfer agent. The polyoxymethylene copolymer can be formed so as to have a relatively low molecular weight and have a relatively great amount of end groups or terminal groups. For instance, the copolymer may contain end groups in an amount greater than 300 mmol/kg.
1 . A polyoxymethylene polymer composition comprising a polyoxymethylene copolymer containing 1,3-dioxolane units in an amount greater than about 60% by weight, the copolymer containing end groups in an amount greater than 300 mmol/kg.
2 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the copolymer contains hemiformal terminal groups in an amount less than about 60 mmol/kg.
3 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the polymer is formed from the reaction product of trioxane, 1,3-dioxolane, a chain transfer agent, and a catalyst.
4 . A polyoxymethylene polymer composition as defined in claim 3 , wherein the polymer has a molecular weight of from about 500 to about 7,000.
5 . A polyoxymethylene polymer composition as defined in claim 3 , wherein the chain transfer agent comprises methylal, butylal, ethylene glycol, diethylene glycol, triethylene glycol or mixtures thereof.
6 . A polyoxymethylene polymer composition as defined in claim 2 , wherein the catalyst comprises triflic acid, perchloric acid, boron trifluoride, or mixtures thereof.
7 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the copolymer contains dioxolane units in an amount from about 55% by weight to about 85% by weight.
8 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the polyoxymethylene copolymer is water miscible.
9 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the polyoxymethylene copolymer has a water uptake at 25° C. and at 50% relative humidity of less than about 2%.
10 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the polyoxymethylene copolymer contains end groups in an amount greater than about 400 mmol/kg and contains hemiformal terminal groups in an amount less than about 50 mmol/kg.
11 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the polyoxymethylene copolymer is water soluble at room temperature.
12 . A polyoxymethylene polymer composition as defined in claim 1 , wherein the polyoxymethylene copolymer has a crystallization point of less than about 12° C.
13 . An emulsion containing the polyoxymethylene polymer composition as defined in claim 1 .
14 . A lubricant composition containing the polyoxymethylene polymer composition as defined in claim 1 .
15 . A hydraulic fluid composition comprising the polyoxymethylene polymer composition as defined in claim 1 .