Animal hide dehairing methods
Methods for preparing an animal hide for chrome tanning are provided. In particular, one or more embodiments include treating the hide with a first enzyme, a second enzyme, and a polysulfide. This treatment facilitates improved removal of hair from the hide. Furthermore, one or more embodiments include various combinations of treating the hide with a third enzyme, a liming agent, a pH-modifying agent, one or more sulfides, and one or more soaking agents. In addition, one or more embodiments include sanitizing the hide and liming the hide to further facilitate the processing of the animal hide into leather.
1. A method for preparing an animal hide for chrome tanning, the method comprising the steps of:
treating the hide with a first enzyme, wherein the first enzyme includes:
a glycosylase enzyme;
treating the hide with a second enzyme after the step of treating with the first enzyme, wherein the second enzyme includes a peptidase; and
treating the hide with a polysulfide after the step of treating with the first enzyme.
2. The method as recited in claim 1 , wherein the step of treating with the polysulfide occurs after the step of treating with the second enzyme.
3. The method as recited in claim 2 , wherein the step of treating with the first enzyme comprises the steps of:
contacting the hide with the first enzyme;
contacting the hide with a soaking agent, wherein the soaking agent includes a degreaser; and
mixing the hide, the first enzyme, and the soaking agent.
4. The method as recited in claim 3 , wherein the step of treating with the second enzyme comprises the steps of:
contacting the hide with the second enzyme;
contacting the hide with a third enzyme, wherein the third enzyme includes a second peptidase; and
mixing the hide, the second enzyme, and the third enzyme.
5. The method as recited in claim 1 , further comprising, after the step of treating with the second enzyme and before the step of treating with the polysulfide, the steps of:
contacting the hide with a pH-modifying agent;
contacting the hide with a first soaking agent, wherein the first soaking agent includes a first degreaser;
contacting the hide with a second soaking agent, wherein the second soaking agent includes a second degreaser; and
mixing the hide, the pH-modifying agent, the first soaking agent, and the second soaking agent.
6. The method as recited in claim 1 , wherein the step of treating with the polysulfide occurs before the step of treating with the second enzyme.
7. The method as recited in claim 6 , wherein the step of treating with the polysulfide comprises the steps of:
contacting the hide with the polysulfide;
contacting the hide with a soaking agent, wherein the soaking agent includes a degreaser; and
mixing the hide, the polysulfide, and the soaking agent.
8. The method as recited in claim 7 , wherein the step of treating with the first enzyme comprises the steps of:
contacting the hide with the first enzyme;
contacting the hide with a pH-modifying agent; and
mixing the hide, the first enzyme, and the pH-modifying agent.
9. The method as recited in claim 1 , further comprising the steps of:
contacting the hide with a soaking agent after the step of treating with the first enzyme and before the step of treating with the polysulfide, wherein the soaking agent includes a degreaser;
mixing the hide and the soaking agent;
contacting the hide with a liming agent after the step of treating with the polysulfide and before the step of treating with the second enzyme; and
mixing the hide and the liming agent.
10. The method as recited in claim 1 , wherein the first enzyme also includes at least one of:
alpha-amylase;
carboxyl esterase; or
a hydrolase enzyme.
11. The method as recited in claim 10 , wherein the first enzyme includes an esterase enzyme.
12. The method as recited in claim 1 , wherein the second enzyme includes a peptidase.
13. The method as recited in claim 12 , wherein the second enzyme includes a glutamyl endopeptidase.
14. The method as recited in claim 1 , wherein treating the hide with a second enzyme includes:
contacting the hide with the second enzyme; and
contacting the hide with a sulfide.
15. The method as recited in claim 14 , wherein the sulfide includes:
sodium hydrosulfide.
16. The method as recited in claim 1 , wherein the polysulfide includes:
sodium polysulfide.
17. The method as recited in claim 1 , wherein the polysulfide includes:
a thioglycolic acid sodium salt.
18. The method as recited in claim 1 , further comprising the step of:
liming the hide after the steps of treating with the second enzyme and treating with the polysulfide.
19. The method as recited in claim 4 , wherein the third enzyme includes a serine endopeptidase.
20. The method as recited in claim 8 , wherein the pH-modifying agent includes:
soda ash.