Process for the production of water and solvent-free hydrogenated nitrile rubbers
The present invention relates to a process for the production of water and solvent-free hydrogenated nitrile rubber polymers, to the hydrogenated nitrile rubbers and the use thereof.
1. A hydrogenated nitrile rubber comprising repeating units derived from at least one conjugated diene and at least one α,β-unsaturated nitrile, wherein the hydrogenated nitrile rubber has a viscosity of a maximum of 1,000 Pa*s at 100° C. and a shear rate of 1/s, wherein the hydrogenated nitrile rubber has less than 0.2 wt % of volatile compounds, wherein the volatile compounds comprise both water and volatile organic compounds, wherein a proportion of the repeating units derived from the α,β-unsaturated nitrile is greater than 43% b.w., based on a total weight of the hydrogenated nitrile rubber, and wherein the hydrogenated nitrile rubber has a weight average molecular weight Mw of 50,000 g/mol or less, and wherein apart from the conjugated diene and the at least one α,β-unsaturated nitrile, the hydrogenated nitrile rubber comprises repeating units of one or more further copolymerizable monomers, and wherein the hydrogenated nitrile rubber has a polydispersity (Mw/Mn) of less than 2.0.
2. The hydrogenated nitrile rubber according to claim 1 , wherein the nitrile rubber has less than 0.175 wt % of volatile compounds, with a residual water concentration less than 0.075 wt %, and a residual volatile organic compounds concentration less than 0.1 wt %.
3. The hydrogenated nitrile rubber according to claim 1 , wherein:
the hydrogenated nitrile rubber comprises 40 up to 57 wt % of the repeat units derived from at least one conjugated diene based on the total polymer, and the at least one conjugated diene comprises 1,3-butadiene, isoprene, 2,3-dimethylbutadiene, piperylene, or mixtures thereof:
the hydrogenated nitrile rubber comprises greater than 43 to 60 wt % of the repeat units derived from at least one α,β-unsaturated nitrile based on the total polymer, and the at least one α,β-unsaturated nitrile comprises acrylonitrile, methacrylonitrile, ethacrylonitrile, or mixtures thereof; and
the hydrogenated nitrile rubber comprises 0.1 to 40 wt % of repeat units derived from at least one additional copolymerizable monomer based on the total polymer, and the at least one additional copolymerizable monomer comprises α,β-unsaturated monocarboxylic acids, their esters or amides; α,β-unsaturated dicarboxylic acids, their mono- or diesters, anhydrides or amides; or mixtures thereof.