Electrodes with directionally restrained active materials and methods of restraint
A method of making an electrode for a lithium ion battery includes providing a restricting media having a main body with opposing planar surfaces and depositing alloying particles on the opposing planar surfaces to form a restrained active particle layer. The restricting media can be a magnetic, electrochemically inactive material with an affinity for the alloying particles. The restricting media restrains expansion of the alloying particles during lithiation to a respective side of the restricting media. Electrodes include a current collector and an electrode material layer adjacent the current collector including the restricting media, the alloying particles deposited on the restricting media to form a restrained active particle layer, and a carbon material in contact with the alloying particles.
1. An electrode for a lithium ion battery, comprising:
a current collector;
an electrode material layer adjacent the current collector comprising:
a restricting media having a main body with opposing planar surfaces;
alloying particles deposited on the restricting media to form a restrained active particle layer, the restricting media configured to restrain expansion of the alloying particles during lithiation; and
a carbon material in contact with the alloying particles, wherein the opposing planar surfaces have apertures therethrough, the aperture diameter being 105% to 110% the diameter of the alloying particles, the alloying particles deposited in the apertures with a binder material such that a perimeter of each aperture forms a belt around one or more of the alloying particles, preventing isotropic expansion of the alloying particles while allowing directional expansion of the alloying particles along a stacking direction of the electrode.
2. The electrode of claim 1 , wherein a thickness of the restricting media is 25% to 60% of the diameter of the active alloying particles.
3. The electrode of claim 1 , wherein the restricting media is a mesh formed from a transitional metal and having apertures of uniform diameter.
4. The electrode of claim 1 , wherein the alloying particles comprise silicon and the material of the restricting media has a higher hardness than the alloying particles.
5. The electrode of claim 1 , wherein the alloying particles have a range of size distribution, and the apertures of the restricting media are formed in varying diameters to accommodate the range of size distribution of the alloying particles.
6. An electrode for a lithium ion battery comprising:
a current collector; and
an electrode material layer adjacent the current collector comprising:
a restricting media having a main body with opposing planar surfaces and having apertures therein;
alloying particles deposited on the restricting media to form a restrained active particle layer, the restricting media configured to restrain expansion of the alloying particles during lithiation; and
a carbon material in contact with the alloying particles, wherein the alloying particles are deposited in the apertures with a binder material, preventing isotropic expansion of the alloying particles while allowing directional expansion of the alloying particles along a stacking direction of the electrode.
7. The electrode of claim 6 , wherein a thickness of the restricting media is 25% to 60% of the diameter of the active alloying particles.
8. The electrode of claim 6 , wherein the restricting media is a mesh formed from a transitional metal and having apertures of uniform diameter.
9. The electrode of claim 6 , wherein the alloying particles comprise silicon and the material of the restricting media has a higher hardness than the alloying particles.
10. The electrode of claim 6 , wherein the alloying particles have a range of size distribution, and the apertures of the restricting media are formed in varying diameters to accommodate the range of size distribution of the alloying particles.