Alkaline cell with improved high rate capacity
View Patent ↗The present disclosure relates generally to an alkaline electrochemical cell, such as a battery, and in particular to an improved gelled anode suitable for use therein. More specifically, the present disclosure relates to a gelled anode that improves anode discharge efficiency by adjusting physical properties such as apparent density.
1. An alkaline electrochemical cell comprising:
a cathode;
a gelled anode mixture, the mixture comprising an anode active material, a gelling agent, and an alkaline electrolyte, wherein the anode active material has an apparent density of from about 2.50 g/cc to about 3.00 g/cc and wherein the anode active material comprises particles having an aspect ratio of from about 7.0 to about 50.0; and,
a separator between the cathode and the anode.
2. The cell of claim 1 , wherein the anode active material has an apparent density of from about 2.60 g/cc to about 2.95 g/cc.
3. The cell of claim 1 , wherein from about 5% to about 40%, by weight, of the total anode active material present in the gelled anode mixture has a particle size of less than about 75 microns.
4. The cell of claim 1 , wherein from about 10% to about 40%, by weight, of the total anode active material present in the gelled anode mixture has a particle size between 75 and 105 microns.
5. The cell of claim 1 , wherein the anode active material comprises a zinc alloy.
6. The cell of claim 5 , wherein the zinc alloy comprises two or more elements selected from indium, bismuth, lead, and aluminum.
7. The cell of claim 6 , wherein the zinc alloy comprises from about 80 ppm to about 250 ppm of bismuth, from about 80 ppm to about 250 ppm of indium, from about 350 ppm to about 600 ppm of lead, and from 80 to 250 ppm of aluminum.
8. The cell of claim 1 , wherein the gelled anode mixture further comprises a gassing inhibitor in an amount of from about 10 ppm to about 150 ppm.
9. The cell of claim 8 , wherein the gassing inhibitor is a phosphate ester.
10. The cell of claim 1 , wherein the electrolyte has a hydroxide concentration of about 30% or less.
11. A gelled anode mixture, the mixture comprising an anode active material, a gelling agent, and an alkaline electrolyte, wherein the anode active material has an apparent density of from about 2.50 g/cc to about 3.00 g/cc and wherein the anode active material comprises particles having an aspect ratio of from about 7.0 to about 50.0.
12. The gelled anode mixture of claim 11 , wherein the anode active material has an apparent density of from about 2.60 g/cc to about 2.95 g/cc.
13. The gelled anode mixture of claim 11 , wherein from about 5% to about 40%, by weight, of the total anode active material present in the gelled anode mixture has a particle size of less than about 75 microns.
14. The gelled anode mixture of claim 11 , wherein from about 10% to about 40%, by weight, of the total anode active material present in the gelled anode mixture has a particle size between 75 and 105 microns.
15. The gelled anode mixture of claim 11 , wherein the anode active material comprises a zinc alloy.
16. The gelled anode mixture of claim 15 , wherein the zinc alloy comprises two or more elements selected from indium, bismuth, lead, and aluminum.
17. The gelled anode mixture of claim 16 , wherein the zinc alloy comprises from about 80 ppm to about 250 ppm of bismuth, from about 80 ppm to about 250 ppm of indium, from about 350 ppm to about 600 ppm of lead, and from 60 to 140 ppm of aluminum.
18. The gelled anode mixture of claim 11 , wherein the gelled anode mixture further comprises a gassing inhibitor in an amount of from about 10 ppm to about 150 ppm.
19. The gelled anode mixture of claim 18 , wherein the gassing inhibitor is a phosphate ester.
20. The gelled anode mixture of claim 11 , wherein the electrolyte has a hydroxide concentration of about 30% or less.