Methods of forming polycrystalline compacts and earth-boring tools including polycrystalline compacts
Methods of forming polycrystalline compacts include subjecting a plurality of grains of hard material interspersed with a catalyst material to high-temperature and high-pressure conditions to form a polycrystalline material having intergranular bonds and interstitial spaces between adjacent grains of the hard material. The catalyst material is disposed in at least some of the interstitial spaces in the polycrystalline material. The methods further comprise substantially removing the catalyst material from the interstitial spaces in at least a portion of the polycrystalline material to form an at least partially leached polycrystalline compact; and removing a portion of the polycrystalline material from which the catalyst material has been substantially removed from the at least partially leached polycrystalline compact. The polycrystalline cutting elements may be secured to a bit body of an earth-boring tool.
1. A method of forming a polycrystalline compact, comprising:
removing at least a portion of a catalyst material from interstitial spaces in at least a portion of a polycrystalline material having intergranular bonds between adjacent grains of hard material to form an at least partially leached polycrystalline compact, wherein the portion of polycrystalline material from which the catalyst material has been removed comprises exposed surfaces of the polycrystalline material extending across a front face and extending between the front face and a back face along a cylindrical sidewall of the polycrystalline material; and
after removing the at least a portion of the catalyst material from the interstitial spaces, polishing at least a portion of the exposed surfaces of polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact to form a surface having a surface roughness less than about 10 μin root mean square (RMS).
2. The method of claim 1 , wherein removing a portion of the polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact comprises forming one or more non-planar areas in the front face of the at least partially leached polycrystalline compact.
3. The method of claim 1 , wherein removing a portion of the polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact comprises exposing the polycrystalline material to electromagnetic radiation to remove at least a portion of the polycrystalline material from which the catalyst material has been substantially removed from the at least partially leached polycrystalline compact.
4. The method of claim 3 , wherein exposing the polycrystalline material to electromagnetic radiation to remove at least a portion of the polycrystalline material from which the catalyst material has been substantially removed from the at least partially leached polycrystalline compact comprises exposing the polycrystalline material to laser irradiation.
5. The method of claim 1 , wherein removing a portion of the polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact comprises forming a chamfer adjacent the front face of the at least partially leached polycrystalline compact.
6. The method of claim 1 , wherein removing at least a portion of a catalyst material from interstitial spaces in at least a portion of a polycrystalline material having intergranular bonds between adjacent grains of hard material to form an at least partially leached polycrystalline compact comprises removing at least a portion of a catalyst material from interstitial spaces in at least a portion of a polycrystalline material bonded to a substrate.
7. The method of claim 1 , wherein removing at least a portion of a catalyst material from interstitial spaces in at least a portion of a polycrystalline material having intergranular bonds between adjacent grains of hard material to form an at least partially leached polycrystalline compact comprises removing at least a portion of a catalyst material from interstitial spaces in polycrystalline diamond.
8. The method of claim 1 , wherein removing at least a portion of the catalyst material from the interstitial spaces in at least a portion of the polycrystalline material comprises forming an interface between a first volume of polycrystalline material and a second volume of polycrystalline material, the first volume of polycrystalline material having a first concentration of the catalyst material and the second volume of polycrystalline material having a second, substantially higher concentration of the catalyst material.
9. The method of claim 1 , wherein removing a portion of the polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact comprises removing a portion of the first volume of polycrystalline material from the at least partially leached polycrystalline compact.
10. The method of claim 1 , further comprising substantially removing the catalyst material from the interstitial spaces in an additional portion of the polycrystalline material having substantial catalyst material therein after removing a portion of the polycrystalline material from which the catalyst material has been substantially removed from the at least partially leached polycrystalline compact.
11. The method of claim 1 , wherein removing at least a portion of the catalyst material from the interstitial spaces in at least a portion of the polycrystalline material comprises acid-leaching the catalyst material from the interstitial spaces in the at least a portion of the polycrystalline material.
12. The method of claim 1 , wherein removing a portion of the polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact comprises forming a recess extending into the polycrystalline material.
13. A method of forming an earth-boring tool, comprising:
forming a polycrystalline cutting element, comprising:
removing at least a portion of a catalyst material from interstitial spaces in at least a portion of a polycrystalline material having intergranular bonds between adjacent grains of hard material to form an at least partially leached polycrystalline compact, wherein the portion of polycrystalline material from which the catalyst material has been removed comprises exposed surfaces of the polycrystalline material extending across a front face and extending between the front face and a back face along a cylindrical sidewall of the polycrystalline material; and
after removing the at least a portion of the catalyst material from the interstitial spaces, polishing a portion of the exposed surfaces of polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact to form a surface having a surface roughness less than about 10 μin root mean square (RMS); and
securing the polycrystalline cutting element to a bit body.
14. The method of claim 13 , wherein forming a polycrystalline cutting element comprises forming the polycrystalline material on a substrate.
15. The method of claim 13 , wherein removing a portion of the polycrystalline material from which the catalyst material has been removed from the at least partially leached polycrystalline compact comprises forming the front face to comprise one or more non-planar surfaces on the at least partially leached polycrystalline compact.
16. The method of claim 13 , further comprising substantially removing an additional portion of the catalyst material from the interstitial spaces in the polycrystalline material having substantial catalyst material therein after removing a portion of the polycrystalline material from which the catalyst material has been substantially removed from the at least partially leached polycrystalline compact and before securing the polycrystalline cutting element to the bit body.
17. A method of forming a polycrystalline diamond compact, comprising:
leaching at least a portion of a catalyst material from interstitial spaces in a first portion of a diamond table to form a partially leached diamond table having intergranular bonds between adjacent grains of diamond, wherein the first portion of the partially leached diamond table comprises exposed surfaces of the partially leached diamond table extending across a front face and extending between the front face and a back face along a cylindrical sidewall of the partially leached diamond table;
polishing at least a portion of the exposed surfaces to remove a portion of the diamond grains from the first portion of the partially leached diamond table and form a surface having a surface roughness less than about 10 μin root mean square (RMS); and
leaching the catalyst material from the interstitial spaces in a second portion of the diamond table.