Stab and ballistic resistant articles and the process of making
View Patent ↗Dimensionally stable open woven fabrics formed from a plurality of high tenacity warp elongate bodies interwoven and bonded with a plurality of transversely disposed, high tenacity weft elongate bodies, composite articles formed therefrom, and to a continuous process for forming the composite articles.
1. A closed, fused, ballistic and stab resistant sheet comprising a plurality of warp elongate bodies interwoven and bonded with a plurality of transversely disposed weft elongate bodies, said warp elongate bodies and weft elongate bodies each comprising thermoplastic high tenacity elongate bodies having a tenacity of at least about 14 g/denier and a tensile modulus of at least about 300 g/denier, and said warp elongate bodies and weft elongate bodies each comprising multifilament fibers or multifilament tapes;
wherein each of said high tenacity elongate bodies comprises a thermoplastic polymer that comprises a polyolefin, a polyester, a polyamide, polyphenylenesulfide, gel spun polyvinyl alcohol, gel spun polytetrafluoroethylene, or a copolymer, block polymer or blend thereof;
the closed, fused sheet having substantially no gaps between adjacent high tenacity warp elongate bodies and wherein said adjacent high tenacity warp elongate bodies do not overlap; and having substantially no gaps between adjacent high tenacity weft elongate bodies and wherein said adjacent high tenacity weft elongate bodies do not overlap;
wherein said warp elongate bodies and said weft elongate bodies are thermally bonded together in the absence of an adhesive coating by melting and then solidifying the thermoplastic polymer of said high tenacity warp elongate bodies and/or the thermoplastic polymer of said high tenacity weft elongate bodies.
2. A ballistic and stab resistant, closed multilayer article comprising at least two fused sheets of claim 1 attached to each other.
3. A ballistic and stab resistant, closed multilayer article of claim 2 , wherein said fused sheets are thermally fused together in the absence of an additional intermediate adhesive resin.
4. The closed, fused, ballistic and stab resistant sheet of claim 1 wherein all of said warp elongate bodies are multifilament fibers and all of said weft elongate bodies are multifilament fibers.
5. The closed, fused, ballistic and stab resistant sheet of claim 1 wherein all of said warp elongate bodies are multifilament tapes and all of said weft elongate bodies are multifilament tapes.
6. The closed, fused, ballistic and stab resistant sheet of claim 1 wherein each of said high tenacity elongate bodies comprise a polyolefin.
7. The closed, fused, ballistic and stab resistant sheet of claim 1 wherein all of said high tenacity elongate bodies comprise polyethylene.
8. The closed, fused ballistic and stab resistant sheet of claim 1 wherein all of said high tenacity elongate bodies comprise ultra-high molecular weight polyethylene.
9. The closed, fused ballistic and stab resistant sheet of claim 1 wherein each of said high tenacity warp elongate bodies and high tenacity weft elongate bodies comprises a multifilament, ultra-high molecular weight polyethylene polymeric tape having a cross-sectional aspect ratio of at least 3:1 and having a width of at least 2.5 mm.
10. The closed, fused ballistic and stab resistant sheet of claim 1 wherein said high tenacity warp elongate bodies comprise untwisted fibrous elongate bodies and said high tenacity weft elongate bodies comprise untwisted fibrous elongate bodies.