Composite reinforcement systems and methods of manufacturing the same
Systems and methods for reinforcing physical structures with composite reinforcement systems are disclosed herein. According to aspects of the present disclosure, a composite reinforcement system includes a carrier formed of a plurality of fibers and a blend of at least two reagents impregnated within the carrier. The at least two reagents are chemically configured to react to form a moisture-curable prepolymer. One reagent of the at least two reagents is an isocyanate, and another reagent of the at least two reagents is an aromatic-group-containing polyol.
1. A repair kit for reinforcement of a physical structure, the repair kit comprising:
a moisture-tight enclosure;
a carrier formed of a plurality of fibers within the moisture-tight enclosure; and
a moisture-curable prepolymer impregnating the carrier in a partially cured state, the moisture-curable prepolymer being formed of at least a polyfunctional aliphatic isocyanate and an aromatic-group-containing polyol as the only polyol;
wherein the polyfunctional aliphatic isocyanate is an isocyanurate-based polyfunctional isocyanate with an isocyanate functionality of greater than two,
the carrier is a fabric or includes unidirectional fiber layers therein,
the aromatic-group-containing polyol is based on a polymer selected from polyester, polyamide, polyurethane, polyurea, and a combination thereof and has aromatic groups in its backbone, and
the polyfunctional aliphatic isocyanate constitutes about 50 wt.% to 90 wt.% of the moisture-curable prepolymer, and the aromatic-group-containing polyol constitutes about 10 wt.% to 50 wt.% of the moisture-curable prepolymer.
2. The repair kit of claim 1 , wherein substantially all of the polyfunctional aliphatic isocyanate and the aromatic-group-containing polyol impregnate the carrier prior to reacting to form the moisture-curable prepolymer in the partially cured state.
3. The repair kit of claim 2 , further comprising:
a filler formed of one or more of wollastonite, halloysite, chopped glass, boron nitride, boron carbide, silicon carbide, tungsten carbide, aluminum oxide, fumed silica, or chopped carbon fibers,
wherein the filler is added as a component of a blend of reagents including the polyfunctional aliphatic isocyanate and the aromatic-group-containing polyol.
4. The repair kit of claim 1 , wherein a ratio of the carrier to the moisture-curable prepolymer in the partially cured state is between about 40:60 to about 60:40 by weight.
5. The repair kit of claim 1 , wherein the plurality of fibers include carbon fibers extending in a generally 0 degree direction and fiberglass fibers extending in a generally 90 degree direction, and the carbon fibers constitute at least about 70 wt % of the carrier and the fiberglass fibers constitute at most about 30 wt % of the carrier.
6. The repair kit of claim 1 , wherein a thickness of the carrier impregnated with the moisture-curable prepolymer in the partially cured state is substantially the same as a thickness of the carrier with the moisture-curable prepolymer in a fully cured state.
7. The repair kit of claim 1 , further comprising:
a disposable film covering one side of the carrier,
wherein the carrier forms a roll with the disposable film separating each successive layer of the carrier within the roll.
8. A kit of components for reinforcing a surface, the kit comprising:
a composite reinforcement system including a carrier and a resin, the carrier configured to be saturated with the resin, the resin including an aliphatic isocyanate-functionalized prepolymer being formed of at least a polyfunctional aliphatic isocyanate and an aromatic-group-containing polyol as the only polyol and being chemically configured to activate and harden after removal of the composite reinforcement system from a protective packaging providing a generally inert interior environment,
wherein the polyfunctional aliphatic isocyanate is an isocyanurate-based polyfunctional isocyanate with an isocyanate functionality of greater than two,
the carrier is a fabric or includes unidirectional fiber layers therein,
the aromatic-group-containing polyol is based on a polymer selected from polyster, polyamide, polyurethane, polyurea, and a combination thereof and has aromatic groups in its backbone, and
the polyfunctional aliphatic isocyanate constitutes about 50 wt. % to 90 wt. % of the moisture-curable prepolymer, and the aromatic-group-containing polyol constitutes about 10 wt. % to 50 wt. % of the moisture-curable polymer.
9. The kit of claim 8 , wherein the carrier is saturated with the resin prior to storage of the kit.
10. A repair kit for reinforcement of a physical structure, comprising:
a pouch defining a moisture-tight enclosure; and
a carrier formed of a plurality of fibers and located within the moisture-tight enclosure, the carrier being pre-impregnated with a blend of at least two reagents, the at least two reagents reacting in the carrier to form a moisture-curable prepolymer, the moisture-curable prepolymer being in a partially cured state within the moisture-tight enclosure,
wherein the moisture-curable prepolymer, after removal from the pouch, is configured to transition to a fully cured and hardened state on the physical structure in response to exposure to moisture, and
wherein the at least two reagents include isocyanate and an aromatic-group-containing polyol as the only polyol,
the isocyanate is an isocyanurate-based polyfunctional aliphatic isocyanate with an isocyanate functionality of greater than two,
the carrier is a fabric or includes unidirectional fiber layers therein, and
the aromatic-group-containing polyol is based on a polymer selected from polyester, polyamide, polyurethane, polyurea, and a combination thereof and has aromatic groups in its backbone, and
the polyfunctional aliphatic isocyanate constitutes about 50 wt. % to 90 wt. % of the moisture-curable prepolymer, and the aromatic-group-containing polyol constitutes about 10 wt. % to 50 wt. % of the moisture-curable prepolymer.
11. The repair kit of claim 10 , wherein the moisture curable prepolymer is an isocyanurate-based polyfunctional aliphatic isocyanate-functionalized prepolymer with aromatic moieties along its prepolymer chain.
12. The repair kit of claim 10 , wherein the pre-impregnated carrier is provided in the pouch as part of a prepreg roll.
13. The repair kit of claim 12 , further including a disposable film attached to plurality of fibers via the partially cured resin to keep adjacent fiber layers within the prepreg roll from attaching to each other.
14. The repair kit of claim 13 , wherein a ratio of the carrier to the moisture-curable prepolymer in the partially cured state is between about 40:60 to about 60:40 by weight.
15. The repair kit of claim 14 , wherein the plurality of fibers include carbon fibers extending in a generally 0 degree direction and fiberglass fibers extending in a generally 90 degree direction, and the carbon fibers constitute at least about 70 wt % of the carrier and the fiberglass fibers constitute at most about 30 wt % of the carrier.
16. The repair kit of claim 1 , wherein the aromatic-group-containing polyol is a polyester-based and includes aromatic groups in its backbone allowing for pi-pi stacking.
17. The repair kit of claim 1 , wherein the aromatic-group-containing polyol constitutes about 10 wt. % to 30 wt. % of the moisture-curable prepolymer.
18. The repair kit of claim 1 , wherein the aromatic-group-containing polyol constitutes about 10 wt. % to 20 wt. % of the moisture-curable prepolymer.