Super absorbent polymer and method of preparing the same
View Patent ↗A super-absorbent polymer satisfying Equation 1 exhibits remarkably improved shape rupture under pressure while maintaining excellent absorption ability. The super-absorbent polymer may be prepared by preparing a base resin by polymerizing a polymeric compound containing an acrylic monomer by using a polyfunctional nitroxide mediated radical polymerization initiator, substituting a terminal of the polymer prepared in the polymerization step with maleic anhydride, cross-linking each maleic anhydride terminal of different polymers prepared in the substitution step by using alkylenediamine having 2 to 8 carbon atoms, drying and grinding the base resin, and surface cross-linking the ground base resin.
1. A super-absorbent polymer having a water-retention ability (B) of 25 g/g or more while satisfying Equation 1 below:
Swollen gel rupture index=(Swollen gel rupture rate under pressure ( A )/Water-retention ability ( B ))≦1.5 [Equation 1]
wherein the swollen gel rupture rate under pressure (A) refers to a percentage of the swollen gel which is obtained by introducing a super-absorbent polymer into a teabag, sealing the teabag, immersing the teabag in 0.9% by weight saline, swelling the polymer for 30 minutes, dehydrating the treated product by a centrifuge under 250 G condition for 3 minutes, providing the remaining super-absorbent swollen gel in a net having 177 micron mesh holes, sealing the open side of the net, placing the net in a holder of the centrifuge, and rotating the net under 1500 G condition for 5 minutes to rupture the swollen gel and allow the same to escape out of the net mesh;
the water-retention ability (B) refers to an absorbency to weight of the initial absorbent polymer, which is obtained by immersing a super-absorbent polymer in 0.9% by weight saline, swelling the polymer for 30 minutes and partially removing water contained in the swollen gel by a centrifuge under 250 G condition for 3 minutes.
2. The super-absorbent polymer according to claim 1 , which satisfies Equation 2 below:
Swollen gel rupture index≦1.0. [Equation 2]
3. The super-absorbent polymer according to claim 1 , which satisfies Equation 3 below:
Swollen gel rupture index≦0.5. [Equation 3]
4. The super-absorbent polymer according to claim 1 , wherein the water-retention ability is 33 g/g or more.