Polymer composition with high XS, high Tm suitable for BOPP processing
View Patent ↗Polypropylene copolymer for biaxially oriented polypropylene (BOPP) with low isotacticity, high melting temperature and low comonomer content.
1. A polypropylene copolymer (R-PP) having
(a) a comonomer content in the range from 0.1 to 3.0 mol-% based on the weight of the polypropylene copolymer (R-PP), wherein the comonomer is ethylene,
(b) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range from 1.0 to 10.0 g/10min,
(c) a melting temperature T m of more than 150.0° C. and
(d) an isotacticity of not more than 92.0%,
(e) a xylene cold soluble fraction (XCS) in the range from 4.0 to 10.0 wt.-%.
2. The polypropylene copolymer (R-PP) according to claim 1 , wherein the polypropylene copolymer (R-PP) has
(a) a Vicat A softening point of below 154.0° C. and/or
(b) a molecular weight distribution (MWD) in the range of 3.0 to 10.0.
3. The polypropylene copolymer (R-PP) according to claim 1 , wherein said polypropylene copolymer (R-PP) comprises two fractions, a first propylene homopolymer fraction (R-PP1) and a second propylene copolymer fraction (R-PP2), wherein said first propylene homopolymer fraction (R-PP1) differs from said second propylene copolymer fraction (R-PP2) in the melt flow rate.
4. The polypropylene copolymer (R-PP) according to claim 3 , wherein
(a) the first propylene homopolymer fraction (R-PP1) and the second propylene copolymer fraction (R-PP2) fulfill together the inequation (Ia),
MFR
(
R
-
PP
1
)
MFR
(
R
-
PP
2
)
≥
1.5
(
Ia
)
wherein
MFR (R-PP1) is the melt flow rate MFR 2 (230° C.) [g/10min] of the first propylene homopolymer fraction (R-PP1) and
MFR (R-PP2) is the melt flow rate MFR 2 (230° C.) [g/10min] of the second propylene copolymer fraction (R-PP2)
and/or
(b) the polypropylene copolymer (R-PP) and the second propylene copolymer fraction (R-PP2) fulfill together the inequation (IIa)
MFR
(
R
-
PP
1
)
MFR
(
R
-
PP
)
≥
1.3
(
IIa
)
wherein
MFR (R-PP) is the melt flow rate MFR 2 (230° C.) [g/10min] of the polypropylene copolymer (R-PP) and
MFR (R-PP1) is the melt flow rate MFR 2 (230° C.) [g/10min] of the first propylene homopolymer fraction (R-PP1).
5. The polypropylene copolymer (R-PP) according to claim 3 , wherein the second propylene copolymer fraction (R-PP2) has a comonomer content in the range from more than 0.1 to 6.0 mol-%.
6. The polypropylene copolymer (R-PP) according to claim 3 , wherein the first propylene homopolymer fraction (R-PP1) has a higher melt flow rate than the second propylene copolymer fraction (R-PP2).
7. A process for preparing a polypropylene copolymer (R-PP) according to claim 3 , comprising a first propylene homopolymer fraction (R-PP1) and a second propylene copolymer fraction (R-PP2), wherein said process is a sequential polymerization process comprising at least two reactors connected in series, wherein said process comprises the steps of
(a) polymerizing in a first reactor (R-1)
(a1) propylene obtaining thereby said first propylene homopolymer fraction (R-PP1),
(b) transferring said first propylene homopolymer fraction (R-PP1) and unreacted monomers from the first reactor (R-1) into a second reactor (R-2),
(c) feeding to said second reactor (R-2)
(c1) propylene and
(c2) ethylene,
(d) polymerizing in said second reactor (R-2) and in the presence of said first propylene homopolymer fraction (R-PP1)
(d1) propylene and
(d2) ethylene,
obtaining said polypropylene copolymer (R-PP) comprising the first propylene homopolymer fraction (R-PP1) and the second propylene copolymer fraction (R-PP2),
wherein the polymerization takes place in the presence of a solid catalyst system (SCS), said solid catalyst system (SCS) comprises
(i) a transition metal (TM) selected from one of the groups 4 to 6 of the periodic table (IUPAC),
(ii) a metal which is selected from one of the groups 1 to 3 of the periodic table (IUPAC),
(iii) an internal electron donor (ID)
(iv) a cocatalyst (Co), and
(v) an external donor (ED).
8. The process according to claim 7 , wherein the solid catalyst system (SCS) comprises a cocatalyst (Co) and a transition metal (TM) in the molar ratio [(Co)/(TM)] above 95.
9. The process according to claim 7 , wherein the solid catalyst system (SCS) comprises a cocatalyst (Co) and a an external donor (ED) in the molar ratio [(Co)/(ED)] above 50.
10. The process according to claim 7 , wherein the solid catalyst system (SCS) comprises an external donor (ED) and a transition metal (TM) in the molar ratio [(ED)/(TM)] below 10.
11. A biaxially oriented polymer film comprising a polypropylene copolymer (R-PP) according to claim 1 .
12. A process for preparing a biaxially oriented polypropylene (BOPP) according to claim 11 comprising the steps of
(a) preparing a polypropylene copolymer (R-PP),
(b) preparing a film comprising the polypropylene copolymer (R-PP), and
(c) biaxially orienting the film.