Organic electroluminescent element and method for manufacturing same
View Patent ↗An organic electroluminescent element contains, on a base, at least a pair of electrodes that are arranged so as to face each other and a group of organic function layers including a light emitting layer, the group of organic function layers being held between the pair of electrodes. The base is a resin base having a thickness within the range of 3-50 μm, and the resin base-side electrode is a transparent positive electrode that is mainly composed of silver and has a thickness within the range of 2-20 nm.
1. An organic electroluminescent device comprising:
a substrate;
a pair of counter electrodes on or above the substrate; and
a luminous layer disposed between the electrodes,
wherein the substrate is a resin substrate having a thickness in the range of 3 to 50 μm, and the electrode adjacent to the resin substrate is a transparent anode primarily composed of silver and having a thickness in the range of 2 to 20 nm, and
wherein the transparent anode is disposed in a neutral region of stress generated when the organic electroluminescent device undergoes bending moment.
2. The organic electroluminescent device according to claim 1 , further comprising an underlying layer on a side of the transparent anode, the side being adjacent to the resin substrate, the underlying layer comprising an organic compound containing a nitrogen or sulfur atom.
3. The organic electroluminescent device according to claim 2 , wherein the organic compound contained in the underlying layer is an organic compound containing a nitrogen atom having an effective unshaved electron pair which is not involved in aromaticity.
4. The organic electroluminescent device according to claim 1 , wherein the resin substrate resides on a light emitting side, the organic electroluminescent device further comprises a gas barrier layer between the resin substrate and the transparent anode, and the gas barrier layer is a modified polysilazane layer.
5. A method of producing an organic electroluminescent device comprising forming a pair of counter electrodes on or above a substrate, and a luminous layer disposed between the electrodes,
wherein the substrate is a resin substrate having a thickness in the range of 3 to 50 μm, the electrode adjacent to the resin substrate is a transparent anode primarily composed. of silver and having a thickness in the range of 2 to 20 nm, and the transparent anode is formed by deposition, and
wherein the transparent anode is disposed in a neutral region of stress generated when the organic electroluminescent device undergoes bending moment.
6. The method of producing an organic electroluminescent device according to claim 5 , wherein an underlying layer comprising an organic compound containing a nitrogen or sulfur atom is formed at a side of the transparent anode, the side being adjacent to the resin substrate.
7. The method of producing an organic electroluminescent device according to claim 5 ,
wherein the resin substrate resides on a light emitting side, a gas barrier layer is formed between the resin substrate and the transparent anode by modifying a polysilazane-containing layer by vacuum UV irradiation.