Ion exchange polymers and a method for making ion exchange polymers
An ion exchange polymer is provided. The ion exchange polymer is a reaction product of a reaction between a crosslinker monomer and a cationic monomer. The crosslinker monomer is a reaction product of a reaction between a first crosslinking monomer and a second crosslinking monomer. Further, the cationic monomer comprises a quaternary ammonium group. A method for making an ion exchange polymer is also provided. The method comprises a step of preparing a curable solution and a step of curing the curable solution. The step of preparing the curable solution comprises mixing a pair of crosslinking monomers, a cationic monomer that comprises a quaternary ammonium group and an acid. A membrane is also provided. The membrane comprises the ion exchange polymer made by the method provided.
1. A method for making an anion exchange membrane comprising steps of:
preparing an aqueous curable solution; applying the curable solution to a support membrane or fabric; and
curing the curable solution,
wherein preparing an aqueous curable solution comprises a step of mixing chemical components and water,
wherein the chemical components comprise a first crosslinking monomer, a second crosslinking monomer, a diallyldialkylammonium salt, and an acid,
wherein the first crosslinking monomer has the following formula:
wherein R′=H or CH 3 , and
the second crosslinking monomer has the following formula:
wherein R=H or CH 3 .
2. The method of claim 1 , wherein the preparing an aqueous curable solution occurs at room temperature.
3. The method of claim 1 , wherein the curing the curable solution comprises a step of heating the curable solution.
4. The method of claim 1 , where the preparing an aqueous curable solution further comprises a step of adding a catalyst.
5. The method of claim 1 , further comprising a step of adding a catalyst after the preparing an aqueous curable solution and before the curing the curable solution.
6. The method of claim 1 , wherein the diallyldialkylammonium salt is diallyldimethylammonium chloride.
7. The method of claim 2 , wherein the curing the curable solution comprises a step of heating the curable solution.
8. The method of claim 2 , wherein the preparing an aqueous curable solution further comprises a step of adding a catalyst.
9. The method of claim 3 , wherein the preparing an aqueous curable solution further comprises a step of adding a catalyst.