Nonaqueous electrolyte secondary battery and method for manufacturing same
View Patent ↗The present invention provides a non-aqueous electrolyte secondary battery with various improved battery characteristics and a method for manufacturing such a non-aqueous electrolyte secondary battery. In the present invention, the battery manufacturing method includes accommodating and sealing a flat battery element ( 4 ) in which a positive electrode plate ( 41 ) and a negative electrode plate ( 42 ) stacked together via a separator ( 43 ), together with a non-aqueous electrolyte including a surplus electrolyte and at least one kind of electrolyte additive, in a laminate film exterior member ( 5 ), and then, subjecting the thus-assembled battery ( 1 ) to charging operation including at least initial charging in a state where a pressure is applied to a flat surface of the battery element from the outside of the exterior member ( 5 ).
1. A manufacturing method of a non-aqueous electrolyte secondary battery, comprising:
assembling the non-aqueous electrolyte secondary battery by accommodating a flat battery element together with a non-aqueous electrolyte and at least one kind of electrolyte additive in a film-like exterior member, the battery element having a positive electrode plate and a negative electrode plate stacked together via a separator, the non-aqueous electrolyte including a surplus electrolyte;
in a state where pressure is applied to a flat surface of the battery element from the outside of the exterior member, subjecting the non-aqueous electrolyte secondary battery to a charging operation including at least initial charging; and
after the charging operation, releasing the non-aqueous electrolyte secondary battery from the applied pressure, such that the surplus electrolyte is shifted to between the electrode plates of the battery element,
wherein the applied pressure during the charging operation including at least initial charging is 0.98×10 −2 MPa to 24.5×10 −2 MPa;
wherein an amount of the electrolyte additive contained in the non-aqueous electrolyte is 3 wt % to 7 wt %;
wherein the electrolyte additive is reduced and decomposed on a negative electrode active material of the negative electrode plate to form a coating film; and
wherein an amount of the electrolyte additive remaining in the non-aqueous electrolyte after the charging operation including at least initial charging is 4000 ppm to 6259 ppm.
2. The manufacturing method of the non-aqueous electrolyte secondary battery according to claim 1 , wherein a thickness of the outer shape of the non-aqueous electrolyte secondary battery under the application of the pressure is in a range of 1.02 to 1.07 times a thickness of the battery element in a stacking direction thereof.
3. The manufacturing method of the non-aqueous electrolyte secondary battery according to claim 1 , wherein an amount of the non-aqueous electrolyte used is 1.1 to 1.6 times as much as a pore volume of the battery element.